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N-(2,4-Dimethyl­phen­yl)-2,2-diphenyl­acetamide

The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent mol­ecules (A and B). Each mol­ecule contains two benzene rings and one dimethyl­benzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in mol­ecule A and 89.25 (16)° in m...

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Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Nayak, Prakash S., Narayana, B., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344457/
https://www.ncbi.nlm.nih.gov/pubmed/22590219
http://dx.doi.org/10.1107/S1600536812014079
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author Fun, Hoong-Kun
Chia, Tze Shyang
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
author_facet Fun, Hoong-Kun
Chia, Tze Shyang
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent mol­ecules (A and B). Each mol­ecule contains two benzene rings and one dimethyl­benzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in mol­ecule A and 89.25 (16)° in mol­ecule B. In mol­ecule A, the dimethyl­benzene ring forms dihedral angles of 89.65 (8) and 42.98 (11)° with the two benzene rings, whereas the corresponding angles are equal to 63.15 (7) and 58.67 (10)° in mol­ecule B. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif in each mol­ecule. In the crystal, mol­ecules are linked by bifurcated (N,C)—H⋯O hydrogen bonds, generating R (2) (1)(6) ring motifs and forming infinite chains along the a axis. The crystal is further stabilized by C—H⋯π and π–π inter­actions with centroid–centroid distances of 3.8543 (18) and 3.930 (2) Å.
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spelling pubmed-33444572012-05-15 N-(2,4-Dimethyl­phen­yl)-2,2-diphenyl­acetamide Fun, Hoong-Kun Chia, Tze Shyang Nayak, Prakash S. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent mol­ecules (A and B). Each mol­ecule contains two benzene rings and one dimethyl­benzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in mol­ecule A and 89.25 (16)° in mol­ecule B. In mol­ecule A, the dimethyl­benzene ring forms dihedral angles of 89.65 (8) and 42.98 (11)° with the two benzene rings, whereas the corresponding angles are equal to 63.15 (7) and 58.67 (10)° in mol­ecule B. An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif in each mol­ecule. In the crystal, mol­ecules are linked by bifurcated (N,C)—H⋯O hydrogen bonds, generating R (2) (1)(6) ring motifs and forming infinite chains along the a axis. The crystal is further stabilized by C—H⋯π and π–π inter­actions with centroid–centroid distances of 3.8543 (18) and 3.930 (2) Å. International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344457/ /pubmed/22590219 http://dx.doi.org/10.1107/S1600536812014079 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chia, Tze Shyang
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
N-(2,4-Dimethyl­phen­yl)-2,2-diphenyl­acetamide
title N-(2,4-Dimethyl­phen­yl)-2,2-diphenyl­acetamide
title_full N-(2,4-Dimethyl­phen­yl)-2,2-diphenyl­acetamide
title_fullStr N-(2,4-Dimethyl­phen­yl)-2,2-diphenyl­acetamide
title_full_unstemmed N-(2,4-Dimethyl­phen­yl)-2,2-diphenyl­acetamide
title_short N-(2,4-Dimethyl­phen­yl)-2,2-diphenyl­acetamide
title_sort n-(2,4-dimethyl­phen­yl)-2,2-diphenyl­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344457/
https://www.ncbi.nlm.nih.gov/pubmed/22590219
http://dx.doi.org/10.1107/S1600536812014079
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