Cargando…
N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide
The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent molecules (A and B). Each molecule contains two benzene rings and one dimethylbenzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in molecule A and 89.25 (16)° in m...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344457/ https://www.ncbi.nlm.nih.gov/pubmed/22590219 http://dx.doi.org/10.1107/S1600536812014079 |
_version_ | 1782231996096839680 |
---|---|
author | Fun, Hoong-Kun Chia, Tze Shyang Nayak, Prakash S. Narayana, B. Sarojini, B. K. |
author_facet | Fun, Hoong-Kun Chia, Tze Shyang Nayak, Prakash S. Narayana, B. Sarojini, B. K. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent molecules (A and B). Each molecule contains two benzene rings and one dimethylbenzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in molecule A and 89.25 (16)° in molecule B. In molecule A, the dimethylbenzene ring forms dihedral angles of 89.65 (8) and 42.98 (11)° with the two benzene rings, whereas the corresponding angles are equal to 63.15 (7) and 58.67 (10)° in molecule B. An intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif in each molecule. In the crystal, molecules are linked by bifurcated (N,C)—H⋯O hydrogen bonds, generating R (2) (1)(6) ring motifs and forming infinite chains along the a axis. The crystal is further stabilized by C—H⋯π and π–π interactions with centroid–centroid distances of 3.8543 (18) and 3.930 (2) Å. |
format | Online Article Text |
id | pubmed-3344457 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33444572012-05-15 N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide Fun, Hoong-Kun Chia, Tze Shyang Nayak, Prakash S. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(22)H(21)NO, consists of two crystallographically independent molecules (A and B). Each molecule contains two benzene rings and one dimethylbenzene ring. The dihedral angle between the two benzene rings is 87.75 (16)° in molecule A and 89.25 (16)° in molecule B. In molecule A, the dimethylbenzene ring forms dihedral angles of 89.65 (8) and 42.98 (11)° with the two benzene rings, whereas the corresponding angles are equal to 63.15 (7) and 58.67 (10)° in molecule B. An intramolecular C—H⋯O hydrogen bond generates an S(6) ring motif in each molecule. In the crystal, molecules are linked by bifurcated (N,C)—H⋯O hydrogen bonds, generating R (2) (1)(6) ring motifs and forming infinite chains along the a axis. The crystal is further stabilized by C—H⋯π and π–π interactions with centroid–centroid distances of 3.8543 (18) and 3.930 (2) Å. International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344457/ /pubmed/22590219 http://dx.doi.org/10.1107/S1600536812014079 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chia, Tze Shyang Nayak, Prakash S. Narayana, B. Sarojini, B. K. N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide |
title |
N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide |
title_full |
N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide |
title_fullStr |
N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide |
title_full_unstemmed |
N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide |
title_short |
N-(2,4-Dimethylphenyl)-2,2-diphenylacetamide |
title_sort | n-(2,4-dimethylphenyl)-2,2-diphenylacetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344457/ https://www.ncbi.nlm.nih.gov/pubmed/22590219 http://dx.doi.org/10.1107/S1600536812014079 |
work_keys_str_mv | AT funhoongkun n24dimethylphenyl22diphenylacetamide AT chiatzeshyang n24dimethylphenyl22diphenylacetamide AT nayakprakashs n24dimethylphenyl22diphenylacetamide AT narayanab n24dimethylphenyl22diphenylacetamide AT sarojinibk n24dimethylphenyl22diphenylacetamide |