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Diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate
In the title compound, C(25)H(27)NO(7), the pyrrolidine ring exhibits an envelope conformation and the benzene rings form a dihedral angle of 33.47 (11)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. Weak C—H⋯O interactions link the dimers into laye...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344464/ https://www.ncbi.nlm.nih.gov/pubmed/22590226 http://dx.doi.org/10.1107/S160053681201392X |
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author | He, Yan-Qin Chen, Jin-Quan |
author_facet | He, Yan-Qin Chen, Jin-Quan |
author_sort | He, Yan-Qin |
collection | PubMed |
description | In the title compound, C(25)H(27)NO(7), the pyrrolidine ring exhibits an envelope conformation and the benzene rings form a dihedral angle of 33.47 (11)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. Weak C—H⋯O interactions link the dimers into layers parallel to the bc plane. |
format | Online Article Text |
id | pubmed-3344464 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33444642012-05-15 Diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate He, Yan-Qin Chen, Jin-Quan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(27)NO(7), the pyrrolidine ring exhibits an envelope conformation and the benzene rings form a dihedral angle of 33.47 (11)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into centrosymmetric dimers. Weak C—H⋯O interactions link the dimers into layers parallel to the bc plane. International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344464/ /pubmed/22590226 http://dx.doi.org/10.1107/S160053681201392X Text en © He and Chen 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers He, Yan-Qin Chen, Jin-Quan Diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate |
title | Diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate |
title_full | Diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate |
title_fullStr | Diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate |
title_full_unstemmed | Diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate |
title_short | Diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate |
title_sort | diethyl 4-methoxyoxalyl-3,5-diphenylpyrrolidine-2,2-dicarboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344464/ https://www.ncbi.nlm.nih.gov/pubmed/22590226 http://dx.doi.org/10.1107/S160053681201392X |
work_keys_str_mv | AT heyanqin diethyl4methoxyoxalyl35diphenylpyrrolidine22dicarboxylate AT chenjinquan diethyl4methoxyoxalyl35diphenylpyrrolidine22dicarboxylate |