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rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one)
The racemic title compound, C(54)H(38)O(2), consists of two C-linked pentaleno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclopentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344468/ https://www.ncbi.nlm.nih.gov/pubmed/22590230 http://dx.doi.org/10.1107/S1600536812014146 |
Sumario: | The racemic title compound, C(54)H(38)O(2), consists of two C-linked pentaleno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclopentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the naphthalene substituent groups of 55.30 (8)°. In each segment, the two phenyl rings have different conformational orientations, with inter-ring dihedral angles of 34.7 (2) and 49.63 (16)°. Each cyclopentane ring has the same relative configuration in its four chiral centres and together with the fused naphthalene ring assumes an overall chair-like conformation. |
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