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rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one)
The racemic title compound, C(54)H(38)O(2), consists of two C-linked pentaleno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclopentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344468/ https://www.ncbi.nlm.nih.gov/pubmed/22590230 http://dx.doi.org/10.1107/S1600536812014146 |
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author | Zhang, Xiangdong Ye, Junwei Gong, Weitao Lin, Yuan Ning, Guiling |
author_facet | Zhang, Xiangdong Ye, Junwei Gong, Weitao Lin, Yuan Ning, Guiling |
author_sort | Zhang, Xiangdong |
collection | PubMed |
description | The racemic title compound, C(54)H(38)O(2), consists of two C-linked pentaleno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclopentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the naphthalene substituent groups of 55.30 (8)°. In each segment, the two phenyl rings have different conformational orientations, with inter-ring dihedral angles of 34.7 (2) and 49.63 (16)°. Each cyclopentane ring has the same relative configuration in its four chiral centres and together with the fused naphthalene ring assumes an overall chair-like conformation. |
format | Online Article Text |
id | pubmed-3344468 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33444682012-05-15 rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) Zhang, Xiangdong Ye, Junwei Gong, Weitao Lin, Yuan Ning, Guiling Acta Crystallogr Sect E Struct Rep Online Organic Papers The racemic title compound, C(54)H(38)O(2), consists of two C-linked pentaleno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclopentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the naphthalene substituent groups of 55.30 (8)°. In each segment, the two phenyl rings have different conformational orientations, with inter-ring dihedral angles of 34.7 (2) and 49.63 (16)°. Each cyclopentane ring has the same relative configuration in its four chiral centres and together with the fused naphthalene ring assumes an overall chair-like conformation. International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344468/ /pubmed/22590230 http://dx.doi.org/10.1107/S1600536812014146 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhang, Xiangdong Ye, Junwei Gong, Weitao Lin, Yuan Ning, Guiling rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
title |
rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
title_full |
rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
title_fullStr |
rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
title_full_unstemmed |
rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
title_short |
rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) |
title_sort | rac-7,7′,9,9′-tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6ah-pentaleno[1,2,3-ij]naphthalen-8-one) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344468/ https://www.ncbi.nlm.nih.gov/pubmed/22590230 http://dx.doi.org/10.1107/S1600536812014146 |
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