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rac-7,7′,9,9′-Tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6aH-penta­leno[1,2,3-ij]naphthalen-8-one)

The racemic title compound, C(54)H(38)O(2), consists of two C-linked penta­leno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclo­pentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between...

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Detalles Bibliográficos
Autores principales: Zhang, Xiangdong, Ye, Junwei, Gong, Weitao, Lin, Yuan, Ning, Guiling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344468/
https://www.ncbi.nlm.nih.gov/pubmed/22590230
http://dx.doi.org/10.1107/S1600536812014146
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author Zhang, Xiangdong
Ye, Junwei
Gong, Weitao
Lin, Yuan
Ning, Guiling
author_facet Zhang, Xiangdong
Ye, Junwei
Gong, Weitao
Lin, Yuan
Ning, Guiling
author_sort Zhang, Xiangdong
collection PubMed
description The racemic title compound, C(54)H(38)O(2), consists of two C-linked penta­leno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclo­pentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the naphthalene substituent groups of 55.30 (8)°. In each segment, the two phenyl rings have different conformational orientations, with inter-ring dihedral angles of 34.7 (2) and 49.63 (16)°. Each cyclo­pentane ring has the same relative configuration in its four chiral centres and together with the fused naphthalene ring assumes an overall chair-like conformation.
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spelling pubmed-33444682012-05-15 rac-7,7′,9,9′-Tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6aH-penta­leno[1,2,3-ij]naphthalen-8-one) Zhang, Xiangdong Ye, Junwei Gong, Weitao Lin, Yuan Ning, Guiling Acta Crystallogr Sect E Struct Rep Online Organic Papers The racemic title compound, C(54)H(38)O(2), consists of two C-linked penta­leno[1,2,3-ij]naphthalenone moieties, the crowded aryl ring substitution on the cyclo­pentane rings forcing the two segments to assume a conformation which has pseudo-twofold rotational symmetry, with a dihedral angle between the naphthalene substituent groups of 55.30 (8)°. In each segment, the two phenyl rings have different conformational orientations, with inter-ring dihedral angles of 34.7 (2) and 49.63 (16)°. Each cyclo­pentane ring has the same relative configuration in its four chiral centres and together with the fused naphthalene ring assumes an overall chair-like conformation. International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344468/ /pubmed/22590230 http://dx.doi.org/10.1107/S1600536812014146 Text en © Zhang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Xiangdong
Ye, Junwei
Gong, Weitao
Lin, Yuan
Ning, Guiling
rac-7,7′,9,9′-Tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6aH-penta­leno[1,2,3-ij]naphthalen-8-one)
title rac-7,7′,9,9′-Tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6aH-penta­leno[1,2,3-ij]naphthalen-8-one)
title_full rac-7,7′,9,9′-Tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6aH-penta­leno[1,2,3-ij]naphthalen-8-one)
title_fullStr rac-7,7′,9,9′-Tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6aH-penta­leno[1,2,3-ij]naphthalen-8-one)
title_full_unstemmed rac-7,7′,9,9′-Tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6aH-penta­leno[1,2,3-ij]naphthalen-8-one)
title_short rac-7,7′,9,9′-Tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6aH-penta­leno[1,2,3-ij]naphthalen-8-one)
title_sort rac-7,7′,9,9′-tetra­phenyl-9a,9a′-bi(7,8,9,9a-tetra­hydro-6ah-penta­leno[1,2,3-ij]naphthalen-8-one)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344468/
https://www.ncbi.nlm.nih.gov/pubmed/22590230
http://dx.doi.org/10.1107/S1600536812014146
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