Bis(5-amino-3-carb­oxy-1H-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate

In the title compound, 2C(3)H(5)N(4)O(2) (+)·H(2)PO(4) (−)·NO(3) (−)·C(3)H(4)N(4)O(2), three independent 5-amino-1H-1,2,4-triazol-3-carb­oxy­lic acid moieties are observed. Two are in the form of cations, while the third is in the zwitterionic form. The triazole rings in the two cations are almost c...

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Autores principales: Berrah, Fadila, Bouchene, Rafika, Bouacida, Sofiane, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344471/
https://www.ncbi.nlm.nih.gov/pubmed/22590233
http://dx.doi.org/10.1107/S1600536812014481
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author Berrah, Fadila
Bouchene, Rafika
Bouacida, Sofiane
Daran, Jean-Claude
author_facet Berrah, Fadila
Bouchene, Rafika
Bouacida, Sofiane
Daran, Jean-Claude
author_sort Berrah, Fadila
collection PubMed
description In the title compound, 2C(3)H(5)N(4)O(2) (+)·H(2)PO(4) (−)·NO(3) (−)·C(3)H(4)N(4)O(2), three independent 5-amino-1H-1,2,4-triazol-3-carb­oxy­lic acid moieties are observed. Two are in the form of cations, while the third is in the zwitterionic form. The triazole rings in the two cations are almost coplanar, making an angle of 4.11 (7)°. Layers parallel to the (20-1) plane, resulting from hydrogen bonding of the organic mol­ecules and the nitrate anions, are linked via H(2)PO(4) (−) infinite zigzag chains running parallel to the c axis. The crystal studied was an inversion twin, with refined components of 0.33 (7) and 0.67 (7).
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spelling pubmed-33444712012-05-15 Bis(5-amino-3-carb­oxy-1H-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate Berrah, Fadila Bouchene, Rafika Bouacida, Sofiane Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 2C(3)H(5)N(4)O(2) (+)·H(2)PO(4) (−)·NO(3) (−)·C(3)H(4)N(4)O(2), three independent 5-amino-1H-1,2,4-triazol-3-carb­oxy­lic acid moieties are observed. Two are in the form of cations, while the third is in the zwitterionic form. The triazole rings in the two cations are almost coplanar, making an angle of 4.11 (7)°. Layers parallel to the (20-1) plane, resulting from hydrogen bonding of the organic mol­ecules and the nitrate anions, are linked via H(2)PO(4) (−) infinite zigzag chains running parallel to the c axis. The crystal studied was an inversion twin, with refined components of 0.33 (7) and 0.67 (7). International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344471/ /pubmed/22590233 http://dx.doi.org/10.1107/S1600536812014481 Text en © Berrah et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Berrah, Fadila
Bouchene, Rafika
Bouacida, Sofiane
Daran, Jean-Claude
Bis(5-amino-3-carb­oxy-1H-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate
title Bis(5-amino-3-carb­oxy-1H-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate
title_full Bis(5-amino-3-carb­oxy-1H-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate
title_fullStr Bis(5-amino-3-carb­oxy-1H-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate
title_full_unstemmed Bis(5-amino-3-carb­oxy-1H-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate
title_short Bis(5-amino-3-carb­oxy-1H-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1H-1,2,4-triazol-4-ium-3-carboxyl­ate
title_sort bis(5-amino-3-carb­oxy-1h-1,2,4-triazol-4-ium) dihydrogenphosphate nitrate 5-amino-1h-1,2,4-triazol-4-ium-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344471/
https://www.ncbi.nlm.nih.gov/pubmed/22590233
http://dx.doi.org/10.1107/S1600536812014481
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AT daranjeanclaude bis5amino3carboxy1h124triazol4iumdihydrogenphosphatenitrate5amino1h124triazol4ium3carboxylate

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