(E)-2-Bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate

In the title compound, C(26)H(24)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 6.27 (6), 33.63 (6) and 69.31 (5)°, respectively, with the pyrazolone ring, the bromo­benzene ring and the terminal phenyl ring. An intra­molecular C—H⋯O hydrogen bond occurs. The crystal packing features...

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Detalles Bibliográficos
Autores principales: Duan, Zhong-Yu, Yang, Lin, Yang, Li-Ping, Liu, Xiu-Wu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344472/
https://www.ncbi.nlm.nih.gov/pubmed/22590234
http://dx.doi.org/10.1107/S160053681201447X
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author Duan, Zhong-Yu
Yang, Lin
Yang, Li-Ping
Liu, Xiu-Wu
author_facet Duan, Zhong-Yu
Yang, Lin
Yang, Li-Ping
Liu, Xiu-Wu
author_sort Duan, Zhong-Yu
collection PubMed
description In the title compound, C(26)H(24)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 6.27 (6), 33.63 (6) and 69.31 (5)°, respectively, with the pyrazolone ring, the bromo­benzene ring and the terminal phenyl ring. An intra­molecular C—H⋯O hydrogen bond occurs. The crystal packing features weak non-classical C—Br⋯O inter­actions [Br⋯O = 3.222 (2) Å] that form inversion-related dimers.
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spelling pubmed-33444722012-05-15 (E)-2-Bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate Duan, Zhong-Yu Yang, Lin Yang, Li-Ping Liu, Xiu-Wu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(24)BrN(3)O(5)S, the central benzene ring makes dihedral angles of 6.27 (6), 33.63 (6) and 69.31 (5)°, respectively, with the pyrazolone ring, the bromo­benzene ring and the terminal phenyl ring. An intra­molecular C—H⋯O hydrogen bond occurs. The crystal packing features weak non-classical C—Br⋯O inter­actions [Br⋯O = 3.222 (2) Å] that form inversion-related dimers. International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344472/ /pubmed/22590234 http://dx.doi.org/10.1107/S160053681201447X Text en © Duan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Duan, Zhong-Yu
Yang, Lin
Yang, Li-Ping
Liu, Xiu-Wu
(E)-2-Bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate
title (E)-2-Bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate
title_full (E)-2-Bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate
title_fullStr (E)-2-Bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate
title_full_unstemmed (E)-2-Bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate
title_short (E)-2-Bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate
title_sort (e)-2-bromo-4-[(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1h-pyrazol-4-yl)imino­meth­yl]-6-meth­oxy­phenyl 4-methyl­benzene­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344472/
https://www.ncbi.nlm.nih.gov/pubmed/22590234
http://dx.doi.org/10.1107/S160053681201447X
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