N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate

In the title compound, C(15)H(13)FN(2)O(3)·CH(3)OH, the dihedral angle between the benzene rings of the benzohydrazone mol­ecule is 5.3 (3)°. The C atom of the meth­oxy group is almost coplanar with its attached ring [deviation = 0.017 (2) Å]. The r.m.s. deviation of the 21 non-H atoms of the hydraz...

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Autor principal: Zong, Qian-Shou
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344474/
https://www.ncbi.nlm.nih.gov/pubmed/22590236
http://dx.doi.org/10.1107/S1600536812012196
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author Zong, Qian-Shou
author_facet Zong, Qian-Shou
author_sort Zong, Qian-Shou
collection PubMed
description In the title compound, C(15)H(13)FN(2)O(3)·CH(3)OH, the dihedral angle between the benzene rings of the benzohydrazone mol­ecule is 5.3 (3)°. The C atom of the meth­oxy group is almost coplanar with its attached ring [deviation = 0.017 (2) Å]. The r.m.s. deviation of the 21 non-H atoms of the hydrazone mol­ecule is 0.106 Å. In the crystal, the components are linked by O(m)—H⋯O(h), N(h)—H⋯O(m) and O(h)—H⋯O(h) (m = methanol and h = hydrazone) hydrogen bonds, forming (001) layers.
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spelling pubmed-33444742012-05-15 N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate Zong, Qian-Shou Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(13)FN(2)O(3)·CH(3)OH, the dihedral angle between the benzene rings of the benzohydrazone mol­ecule is 5.3 (3)°. The C atom of the meth­oxy group is almost coplanar with its attached ring [deviation = 0.017 (2) Å]. The r.m.s. deviation of the 21 non-H atoms of the hydrazone mol­ecule is 0.106 Å. In the crystal, the components are linked by O(m)—H⋯O(h), N(h)—H⋯O(m) and O(h)—H⋯O(h) (m = methanol and h = hydrazone) hydrogen bonds, forming (001) layers. International Union of Crystallography 2012-04-06 /pmc/articles/PMC3344474/ /pubmed/22590236 http://dx.doi.org/10.1107/S1600536812012196 Text en © Qian-Shou Zong 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zong, Qian-Shou
N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate
title N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate
title_full N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate
title_fullStr N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate
title_full_unstemmed N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate
title_short N′-(3-Fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate
title_sort n′-(3-fluoro­benzyl­idene)-4-hy­droxy-3-meth­oxy­benzohydrazide methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344474/
https://www.ncbi.nlm.nih.gov/pubmed/22590236
http://dx.doi.org/10.1107/S1600536812012196
work_keys_str_mv AT zongqianshou n3fluorobenzylidene4hydroxy3methoxybenzohydrazidemethanolmonosolvate

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