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3-[(N-Methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione

In the title compound, C(14)H(13)N(3)OS(2), the thio­phene ring is disordered over two orientations by ca 180° about the C—C bond axis linking the ring to the rest of the mol­ecule, with a site-occupancy ratio of 0.651 (5):0.349 (5). The central 1,3,4-oxadiazole-2(3H)-thione ring forms dihedral angl...

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Autores principales: El-Emam, Ali A., Al-Omar, Mohamed A., Ghabbour, Hazem A., Fun, Hoong-Kun, Chia, Tze Shyang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344480/
https://www.ncbi.nlm.nih.gov/pubmed/22590242
http://dx.doi.org/10.1107/S1600536812014419
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author El-Emam, Ali A.
Al-Omar, Mohamed A.
Ghabbour, Hazem A.
Fun, Hoong-Kun
Chia, Tze Shyang
author_facet El-Emam, Ali A.
Al-Omar, Mohamed A.
Ghabbour, Hazem A.
Fun, Hoong-Kun
Chia, Tze Shyang
author_sort El-Emam, Ali A.
collection PubMed
description In the title compound, C(14)H(13)N(3)OS(2), the thio­phene ring is disordered over two orientations by ca 180° about the C—C bond axis linking the ring to the rest of the mol­ecule, with a site-occupancy ratio of 0.651 (5):0.349 (5). The central 1,3,4-oxadiazole-2(3H)-thione ring forms dihedral angles of 9.2 (5), 4.6 (11) and 47.70 (7)° with the major and minor parts of the disordered thio­phene ring and the terminal phenyl ring, respectively. In the crystal, no significant inter­molecular hydrogen bonds are observed. The crystal packing is stabilized by π–π inter­actions [centroid–centroid distance = 3.589 (2) Å].
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spelling pubmed-33444802012-05-15 3-[(N-Methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione El-Emam, Ali A. Al-Omar, Mohamed A. Ghabbour, Hazem A. Fun, Hoong-Kun Chia, Tze Shyang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(13)N(3)OS(2), the thio­phene ring is disordered over two orientations by ca 180° about the C—C bond axis linking the ring to the rest of the mol­ecule, with a site-occupancy ratio of 0.651 (5):0.349 (5). The central 1,3,4-oxadiazole-2(3H)-thione ring forms dihedral angles of 9.2 (5), 4.6 (11) and 47.70 (7)° with the major and minor parts of the disordered thio­phene ring and the terminal phenyl ring, respectively. In the crystal, no significant inter­molecular hydrogen bonds are observed. The crystal packing is stabilized by π–π inter­actions [centroid–centroid distance = 3.589 (2) Å]. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344480/ /pubmed/22590242 http://dx.doi.org/10.1107/S1600536812014419 Text en © El-Emam et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
El-Emam, Ali A.
Al-Omar, Mohamed A.
Ghabbour, Hazem A.
Fun, Hoong-Kun
Chia, Tze Shyang
3-[(N-Methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione
title 3-[(N-Methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione
title_full 3-[(N-Methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione
title_fullStr 3-[(N-Methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione
title_full_unstemmed 3-[(N-Methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione
title_short 3-[(N-Methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3H)-thione
title_sort 3-[(n-methyl­anilino)meth­yl]-5-(thio­phen-2-yl)-1,3,4-oxadiazole-2(3h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344480/
https://www.ncbi.nlm.nih.gov/pubmed/22590242
http://dx.doi.org/10.1107/S1600536812014419
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