N-(3,4-Difluoro­phen­yl)-2,2-diphenyl­acetamide

In the title compound, C(20)H(15)F(2)NO, the mean plane of the acetamide group makes dihedral angles of 88.26 (6), 78.30 (7) and 9.83 (6)° with the two terminal benzene rings and difluoro-substituted benzene ring, respectively. One F atom is disordered over two orientations rotated by 180°, with a s...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Ooi, Chin Wei, Nayak, Prakash S., Narayana, B., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344483/
https://www.ncbi.nlm.nih.gov/pubmed/22590245
http://dx.doi.org/10.1107/S1600536812014675
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author Fun, Hoong-Kun
Ooi, Chin Wei
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
author_facet Fun, Hoong-Kun
Ooi, Chin Wei
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(20)H(15)F(2)NO, the mean plane of the acetamide group makes dihedral angles of 88.26 (6), 78.30 (7) and 9.83 (6)° with the two terminal benzene rings and difluoro-substituted benzene ring, respectively. One F atom is disordered over two orientations rotated by 180°, with a site-occupancy ratio of 0.557 (2):0.443 (2). An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds into chains along the c axis. The crystal structure is further consolidated by C—H⋯π inter­actions.
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spelling pubmed-33444832012-05-15 N-(3,4-Difluoro­phen­yl)-2,2-diphenyl­acetamide Fun, Hoong-Kun Ooi, Chin Wei Nayak, Prakash S. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(15)F(2)NO, the mean plane of the acetamide group makes dihedral angles of 88.26 (6), 78.30 (7) and 9.83 (6)° with the two terminal benzene rings and difluoro-substituted benzene ring, respectively. One F atom is disordered over two orientations rotated by 180°, with a site-occupancy ratio of 0.557 (2):0.443 (2). An intra­molecular C—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds into chains along the c axis. The crystal structure is further consolidated by C—H⋯π inter­actions. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344483/ /pubmed/22590245 http://dx.doi.org/10.1107/S1600536812014675 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Ooi, Chin Wei
Nayak, Prakash S.
Narayana, B.
Sarojini, B. K.
N-(3,4-Difluoro­phen­yl)-2,2-diphenyl­acetamide
title N-(3,4-Difluoro­phen­yl)-2,2-diphenyl­acetamide
title_full N-(3,4-Difluoro­phen­yl)-2,2-diphenyl­acetamide
title_fullStr N-(3,4-Difluoro­phen­yl)-2,2-diphenyl­acetamide
title_full_unstemmed N-(3,4-Difluoro­phen­yl)-2,2-diphenyl­acetamide
title_short N-(3,4-Difluoro­phen­yl)-2,2-diphenyl­acetamide
title_sort n-(3,4-difluoro­phen­yl)-2,2-diphenyl­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344483/
https://www.ncbi.nlm.nih.gov/pubmed/22590245
http://dx.doi.org/10.1107/S1600536812014675
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