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N-(2-{[7-(2-Anilinoethoxy)-3,6-dibromonaphthalen-2-yl]oxy}ethyl)aniline
In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two –CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a full...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344487/ https://www.ncbi.nlm.nih.gov/pubmed/22590249 http://dx.doi.org/10.1107/S1600536812014808 |
Sumario: | In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two –CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a fully extended all-cis conformation with respect to the naphthalene and phenyl rings [N—C—C—O torsion angles = 68.6 (4) and 60.5 (4)°]. In the crystal, one of the N—H groups forms bifurcated N—H⋯(Br,O) hydrogen bonds, which link the molecules into inversion-related dimers. The centrosymmetric dimers are aggregated via pairs of C—H⋯π interactions into sheets parallel to (110). |
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