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N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline

In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two –CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a full...

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Detalles Bibliográficos
Autores principales: Zong, Qian-Shou, Wu, Jian-Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344487/
https://www.ncbi.nlm.nih.gov/pubmed/22590249
http://dx.doi.org/10.1107/S1600536812014808
Descripción
Sumario:In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two –CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a fully extended all-cis conformation with respect to the naphthalene and phenyl rings [N—C—C—O torsion angles = 68.6 (4) and 60.5 (4)°]. In the crystal, one of the N—H groups forms bifurcated N—H⋯(Br,O) hydrogen bonds, which link the mol­ecules into inversion-related dimers. The centrosymmetric dimers are aggregated via pairs of C—H⋯π inter­actions into sheets parallel to (110).