N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline

In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two –CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a full...

Descripción completa

Detalles Bibliográficos
Autores principales: Zong, Qian-Shou, Wu, Jian-Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344487/
https://www.ncbi.nlm.nih.gov/pubmed/22590249
http://dx.doi.org/10.1107/S1600536812014808
_version_ 1782232002821357568
author Zong, Qian-Shou
Wu, Jian-Yi
author_facet Zong, Qian-Shou
Wu, Jian-Yi
author_sort Zong, Qian-Shou
collection PubMed
description In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two –CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a fully extended all-cis conformation with respect to the naphthalene and phenyl rings [N—C—C—O torsion angles = 68.6 (4) and 60.5 (4)°]. In the crystal, one of the N—H groups forms bifurcated N—H⋯(Br,O) hydrogen bonds, which link the mol­ecules into inversion-related dimers. The centrosymmetric dimers are aggregated via pairs of C—H⋯π inter­actions into sheets parallel to (110).
format Online
Article
Text
id pubmed-3344487
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33444872012-05-15 N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline Zong, Qian-Shou Wu, Jian-Yi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(24)Br(2)N(2)O(2), the central naphthalene system carries two Br atoms and two –CH(2)CH(2)NHC(6)H(5) substituents. The phenyl rings of the latter residues are inclined at 74.17 (17) and 51.4 (2)° with respect to the naphthalene ring system. Each alkyl chain adopts a fully extended all-cis conformation with respect to the naphthalene and phenyl rings [N—C—C—O torsion angles = 68.6 (4) and 60.5 (4)°]. In the crystal, one of the N—H groups forms bifurcated N—H⋯(Br,O) hydrogen bonds, which link the mol­ecules into inversion-related dimers. The centrosymmetric dimers are aggregated via pairs of C—H⋯π inter­actions into sheets parallel to (110). International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344487/ /pubmed/22590249 http://dx.doi.org/10.1107/S1600536812014808 Text en © Zong and Wu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zong, Qian-Shou
Wu, Jian-Yi
N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline
title N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline
title_full N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline
title_fullStr N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline
title_full_unstemmed N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline
title_short N-(2-{[7-(2-Anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline
title_sort n-(2-{[7-(2-anilinoeth­oxy)-3,6-dibromo­naphthalen-2-yl]­oxy}eth­yl)aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344487/
https://www.ncbi.nlm.nih.gov/pubmed/22590249
http://dx.doi.org/10.1107/S1600536812014808
work_keys_str_mv AT zongqianshou n272anilinoethoxy36dibromonaphthalen2yloxyethylaniline
AT wujianyi n272anilinoethoxy36dibromonaphthalen2yloxyethylaniline

Ejemplares similares