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2-(4-Aminophenyl)-3,4,5,6-tetrahydropyrimidin-1-ium chloride
In the title compound, C(10)H(14)N(3) (+)·Cl(−), the tetrahydropyridinium ring of the cation, which adopts a slightly distorted envelope conformation, is disordered over two orientations with an occupancy ratio of 0.653 (5):0.347 (5). The amidinium fragment of the major conformer is twisted relati...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344492/ https://www.ncbi.nlm.nih.gov/pubmed/22590254 http://dx.doi.org/10.1107/S1600536812014493 |
Sumario: | In the title compound, C(10)H(14)N(3) (+)·Cl(−), the tetrahydropyridinium ring of the cation, which adopts a slightly distorted envelope conformation, is disordered over two orientations with an occupancy ratio of 0.653 (5):0.347 (5). The amidinium fragment of the major conformer is twisted relative to the benzene ring by 22.5 (6)° and the two C—N bond lengths of this fragment are similar [1.3228 (16) and 1.319 (2) Å]. In the crystal, the chloride anions are involved in three N—H⋯Cl hydrogen bonds, which link the components into a two-dimensional hydrogen-bonded network parallel to (010). |
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