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2-(4-Amino­phen­yl)-3,4,5,6-tetra­hydro­pyrimidin-1-ium chloride

In the title compound, C(10)H(14)N(3) (+)·Cl(−), the tetra­hydro­pyridinium ring of the cation, which adopts a slightly distorted envelope conformation, is disordered over two orientations with an occupancy ratio of 0.653 (5):0.347 (5). The amidinium fragment of the major conformer is twisted relati...

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Detalles Bibliográficos
Autores principales: Molčanov, Krešimir, Stolić, Ivana, Kojić-Prodić, Biserka, Kovačević, Goran, Bajić, Miroslav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344492/
https://www.ncbi.nlm.nih.gov/pubmed/22590254
http://dx.doi.org/10.1107/S1600536812014493
Descripción
Sumario:In the title compound, C(10)H(14)N(3) (+)·Cl(−), the tetra­hydro­pyridinium ring of the cation, which adopts a slightly distorted envelope conformation, is disordered over two orientations with an occupancy ratio of 0.653 (5):0.347 (5). The amidinium fragment of the major conformer is twisted relative to the benzene ring by 22.5 (6)° and the two C—N bond lengths of this fragment are similar [1.3228 (16) and 1.319 (2) Å]. In the crystal, the chloride anions are involved in three N—H⋯Cl hydrogen bonds, which link the components into a two-dimensional hydrogen-bonded network parallel to (010).