1,1,2,2-Tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate

The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(−)·2C(3)H(6)O, crystallizes with two acetone solvent mol­ecules per asymmetric unit. In the dication, both amidinium units are twisted about the central C—C single bond by 63.8 (3)° and the positive charges are delocalized over both N—C—N planes....

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Detalles Bibliográficos
Autores principales: Tiritiris, Ioannis, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344502/
https://www.ncbi.nlm.nih.gov/pubmed/22590264
http://dx.doi.org/10.1107/S1600536812015085
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author Tiritiris, Ioannis
Kantlehner, Willi
author_facet Tiritiris, Ioannis
Kantlehner, Willi
author_sort Tiritiris, Ioannis
collection PubMed
description The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(−)·2C(3)H(6)O, crystallizes with two acetone solvent mol­ecules per asymmetric unit. In the dication, both amidinium units are twisted about the central C—C single bond by 63.8 (3)° and the positive charges are delocalized over both N—C—N planes.
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spelling pubmed-33445022012-05-15 1,1,2,2-Tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate Tiritiris, Ioannis Kantlehner, Willi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(24)N(4) (2+)·2C(24)H(20)B(−)·2C(3)H(6)O, crystallizes with two acetone solvent mol­ecules per asymmetric unit. In the dication, both amidinium units are twisted about the central C—C single bond by 63.8 (3)° and the positive charges are delocalized over both N—C—N planes. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344502/ /pubmed/22590264 http://dx.doi.org/10.1107/S1600536812015085 Text en © Tiritiris and Kantlehner 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tiritiris, Ioannis
Kantlehner, Willi
1,1,2,2-Tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate
title 1,1,2,2-Tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate
title_full 1,1,2,2-Tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate
title_fullStr 1,1,2,2-Tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate
title_full_unstemmed 1,1,2,2-Tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate
title_short 1,1,2,2-Tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate
title_sort 1,1,2,2-tetra­kis(dimethyl­amino)­ethane-1,2-diium bis­(tetra­phenyl­borate) acetone disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344502/
https://www.ncbi.nlm.nih.gov/pubmed/22590264
http://dx.doi.org/10.1107/S1600536812015085
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