(E)-Methyl 2-({2-eth­oxy-6-[(E)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate

In the title compound, C(20)H(21)NO(5), the dihedral angle between the mean planes through the two rings is 47.1 (8)°. The enoate group assumes an extended conformation. The hy­droxy­ethanimine group is essentially coplanar with the benzene ring, the largest deviation from the mean plane being 0.061...

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Detalles Bibliográficos
Autores principales: Govindan, E., Ganesh, G., Srinivasan, J., Bakthadoss, M., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344504/
https://www.ncbi.nlm.nih.gov/pubmed/22590266
http://dx.doi.org/10.1107/S1600536812014596
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author Govindan, E.
Ganesh, G.
Srinivasan, J.
Bakthadoss, M.
SubbiahPandi, A.
author_facet Govindan, E.
Ganesh, G.
Srinivasan, J.
Bakthadoss, M.
SubbiahPandi, A.
author_sort Govindan, E.
collection PubMed
description In the title compound, C(20)H(21)NO(5), the dihedral angle between the mean planes through the two rings is 47.1 (8)°. The enoate group assumes an extended conformation. The hy­droxy­ethanimine group is essentially coplanar with the benzene ring, the largest deviation from the mean plane being 0.061 (1) Å for the O atom. In the crystal, mol­ecules are linked into cyclic centrosymmetric dimers with an R (2) (2)(6) motif via pairs of O—H⋯N hydrogen bonds. Inter­molecular C—H⋯O hydrogen bonds form a C(8) chain along the b axis. The crystal packing is further stabilized by C—H⋯π inter­actions.
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spelling pubmed-33445042012-05-15 (E)-Methyl 2-({2-eth­oxy-6-[(E)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate Govindan, E. Ganesh, G. Srinivasan, J. Bakthadoss, M. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(21)NO(5), the dihedral angle between the mean planes through the two rings is 47.1 (8)°. The enoate group assumes an extended conformation. The hy­droxy­ethanimine group is essentially coplanar with the benzene ring, the largest deviation from the mean plane being 0.061 (1) Å for the O atom. In the crystal, mol­ecules are linked into cyclic centrosymmetric dimers with an R (2) (2)(6) motif via pairs of O—H⋯N hydrogen bonds. Inter­molecular C—H⋯O hydrogen bonds form a C(8) chain along the b axis. The crystal packing is further stabilized by C—H⋯π inter­actions. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344504/ /pubmed/22590266 http://dx.doi.org/10.1107/S1600536812014596 Text en © Govindan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Govindan, E.
Ganesh, G.
Srinivasan, J.
Bakthadoss, M.
SubbiahPandi, A.
(E)-Methyl 2-({2-eth­oxy-6-[(E)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate
title (E)-Methyl 2-({2-eth­oxy-6-[(E)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate
title_full (E)-Methyl 2-({2-eth­oxy-6-[(E)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate
title_fullStr (E)-Methyl 2-({2-eth­oxy-6-[(E)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate
title_full_unstemmed (E)-Methyl 2-({2-eth­oxy-6-[(E)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate
title_short (E)-Methyl 2-({2-eth­oxy-6-[(E)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate
title_sort (e)-methyl 2-({2-eth­oxy-6-[(e)-(hy­droxy­imino)­meth­yl]phen­oxy}meth­yl)-3-phenyl­acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344504/
https://www.ncbi.nlm.nih.gov/pubmed/22590266
http://dx.doi.org/10.1107/S1600536812014596
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AT bakthadossm emethyl22ethoxy6ehydroxyiminomethylphenoxymethyl3phenylacrylate
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