1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone

The title compound C(8)H(8)N(2)Se, is the product of the reaction of 2-chloro-1-methyl­benzimidazole with sodium hydro­selenide. The mol­ecule is almost planar (r.m.s. deviation = 0.041 Å) owing to the presence of the long chain of conjugated bonds (Se=C—NMe—C=C—C=C—C=C—NH). The C=Se bond length [1....

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Autores principales: Mammadova, Gunay Z., Matsulevich, Zhanna V., Osmanov, Vladimir K., Borisov, Alexander V., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344510/
https://www.ncbi.nlm.nih.gov/pubmed/22590272
http://dx.doi.org/10.1107/S1600536812013700
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author Mammadova, Gunay Z.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
author_facet Mammadova, Gunay Z.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
author_sort Mammadova, Gunay Z.
collection PubMed
description The title compound C(8)H(8)N(2)Se, is the product of the reaction of 2-chloro-1-methyl­benzimidazole with sodium hydro­selenide. The mol­ecule is almost planar (r.m.s. deviation = 0.041 Å) owing to the presence of the long chain of conjugated bonds (Se=C—NMe—C=C—C=C—C=C—NH). The C=Se bond length [1.838 (2) Å] corresponds well to those found in the close analogs and indicates its pronounced double-bond character. In the crystal, mol­ecules form helicoidal chains along the b axis by means of N—H⋯Se hydrogen bonds.
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spelling pubmed-33445102012-05-15 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone Mammadova, Gunay Z. Matsulevich, Zhanna V. Osmanov, Vladimir K. Borisov, Alexander V. Khrustalev, Victor N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound C(8)H(8)N(2)Se, is the product of the reaction of 2-chloro-1-methyl­benzimidazole with sodium hydro­selenide. The mol­ecule is almost planar (r.m.s. deviation = 0.041 Å) owing to the presence of the long chain of conjugated bonds (Se=C—NMe—C=C—C=C—C=C—NH). The C=Se bond length [1.838 (2) Å] corresponds well to those found in the close analogs and indicates its pronounced double-bond character. In the crystal, mol­ecules form helicoidal chains along the b axis by means of N—H⋯Se hydrogen bonds. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344510/ /pubmed/22590272 http://dx.doi.org/10.1107/S1600536812013700 Text en © Mammadova et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mammadova, Gunay Z.
Matsulevich, Zhanna V.
Osmanov, Vladimir K.
Borisov, Alexander V.
Khrustalev, Victor N.
1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone
title 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone
title_full 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone
title_fullStr 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone
title_full_unstemmed 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone
title_short 1-Methyl-2,3-dihydro-1H-benzimidazole-2-selone
title_sort 1-methyl-2,3-dihydro-1h-benzimidazole-2-selone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344510/
https://www.ncbi.nlm.nih.gov/pubmed/22590272
http://dx.doi.org/10.1107/S1600536812013700
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