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4-[(2′-Cyanobiphenyl-4-yl)methyl]morpholin-4-ium hexafluoridophosphate
In the cation of the title compound, C(18)H(19)N(2)O(+)·PF(6) (−), the morpholine ring adopts the usual chair conformation and the dihedral angle between the benzene rings is 67.55 (11)°. The F atoms of the anion are disordered over two orientations with a refined occupancy ratio of 0.65 (2):0.35 (2...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344511/ https://www.ncbi.nlm.nih.gov/pubmed/22590273 http://dx.doi.org/10.1107/S160053681201358X |
| Sumario: | In the cation of the title compound, C(18)H(19)N(2)O(+)·PF(6) (−), the morpholine ring adopts the usual chair conformation and the dihedral angle between the benzene rings is 67.55 (11)°. The F atoms of the anion are disordered over two orientations with a refined occupancy ratio of 0.65 (2):0.35 (2). In the crystal, intermolecular N—H⋯N hydrogen bonds link the cations into chains parallel to the c axis. The crystal packing is further enforced by interionic C—H⋯F hydrogen bonds. |
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