4-[(2′-Cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate

In the cation of the title compound, C(18)H(19)N(2)O(+)·PF(6) (−), the morpholine ring adopts the usual chair conformation and the dihedral angle between the benzene rings is 67.55 (11)°. The F atoms of the anion are disordered over two orientations with a refined occupancy ratio of 0.65 (2):0.35 (2...

Descripción completa

Detalles Bibliográficos
Autores principales: Xue, Hua Yu, Wang, Shi Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344511/
https://www.ncbi.nlm.nih.gov/pubmed/22590273
http://dx.doi.org/10.1107/S160053681201358X
_version_ 1782232008220475392
author Xue, Hua Yu
Wang, Shi Juan
author_facet Xue, Hua Yu
Wang, Shi Juan
author_sort Xue, Hua Yu
collection PubMed
description In the cation of the title compound, C(18)H(19)N(2)O(+)·PF(6) (−), the morpholine ring adopts the usual chair conformation and the dihedral angle between the benzene rings is 67.55 (11)°. The F atoms of the anion are disordered over two orientations with a refined occupancy ratio of 0.65 (2):0.35 (2). In the crystal, inter­molecular N—H⋯N hydrogen bonds link the cations into chains parallel to the c axis. The crystal packing is further enforced by inter­ionic C—H⋯F hydrogen bonds.
format Online
Article
Text
id pubmed-3344511
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33445112012-05-15 4-[(2′-Cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate Xue, Hua Yu Wang, Shi Juan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title compound, C(18)H(19)N(2)O(+)·PF(6) (−), the morpholine ring adopts the usual chair conformation and the dihedral angle between the benzene rings is 67.55 (11)°. The F atoms of the anion are disordered over two orientations with a refined occupancy ratio of 0.65 (2):0.35 (2). In the crystal, inter­molecular N—H⋯N hydrogen bonds link the cations into chains parallel to the c axis. The crystal packing is further enforced by inter­ionic C—H⋯F hydrogen bonds. International Union of Crystallography 2012-04-13 /pmc/articles/PMC3344511/ /pubmed/22590273 http://dx.doi.org/10.1107/S160053681201358X Text en © Xue and Wang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xue, Hua Yu
Wang, Shi Juan
4-[(2′-Cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate
title 4-[(2′-Cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate
title_full 4-[(2′-Cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate
title_fullStr 4-[(2′-Cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate
title_full_unstemmed 4-[(2′-Cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate
title_short 4-[(2′-Cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate
title_sort 4-[(2′-cyano­biphenyl-4-yl)meth­yl]morpholin-4-ium hexa­fluoridophosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344511/
https://www.ncbi.nlm.nih.gov/pubmed/22590273
http://dx.doi.org/10.1107/S160053681201358X
work_keys_str_mv AT xuehuayu 42cyanobiphenyl4ylmethylmorpholin4iumhexafluoridophosphate
AT wangshijuan 42cyanobiphenyl4ylmethylmorpholin4iumhexafluoridophosphate

Ejemplares similares