(Z)-2-(4-Chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2H)-one

The mol­ecule of the title compound, C(16)H(9)ClN(2)OS, is approximately planar, the dihedral angle between the thia­zolo[3,2-a]benzimidazole ring system and the 4-chloro­phenyl ring being 2.10 (5)°. An intra­molecular C—H⋯S inter­action generates an S(6) ring motif. In the crystal, mol­ecules are s...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Abdel-Aziz, Hatem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344520/
https://www.ncbi.nlm.nih.gov/pubmed/22590282
http://dx.doi.org/10.1107/S1600536812015516
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author Fun, Hoong-Kun
Chantrapromma, Suchada
Abdel-Aziz, Hatem A.
author_facet Fun, Hoong-Kun
Chantrapromma, Suchada
Abdel-Aziz, Hatem A.
author_sort Fun, Hoong-Kun
collection PubMed
description The mol­ecule of the title compound, C(16)H(9)ClN(2)OS, is approximately planar, the dihedral angle between the thia­zolo[3,2-a]benzimidazole ring system and the 4-chloro­phenyl ring being 2.10 (5)°. An intra­molecular C—H⋯S inter­action generates an S(6) ring motif. In the crystal, mol­ecules are stacked into columns along the b axis by π–π inter­actions with centroid–centroid distances of 3.6495 (7)–3.9546 (8) Å.
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spelling pubmed-33445202012-05-15 (Z)-2-(4-Chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2H)-one Fun, Hoong-Kun Chantrapromma, Suchada Abdel-Aziz, Hatem A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(16)H(9)ClN(2)OS, is approximately planar, the dihedral angle between the thia­zolo[3,2-a]benzimidazole ring system and the 4-chloro­phenyl ring being 2.10 (5)°. An intra­molecular C—H⋯S inter­action generates an S(6) ring motif. In the crystal, mol­ecules are stacked into columns along the b axis by π–π inter­actions with centroid–centroid distances of 3.6495 (7)–3.9546 (8) Å. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344520/ /pubmed/22590282 http://dx.doi.org/10.1107/S1600536812015516 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chantrapromma, Suchada
Abdel-Aziz, Hatem A.
(Z)-2-(4-Chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2H)-one
title (Z)-2-(4-Chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2H)-one
title_full (Z)-2-(4-Chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2H)-one
title_fullStr (Z)-2-(4-Chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2H)-one
title_full_unstemmed (Z)-2-(4-Chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2H)-one
title_short (Z)-2-(4-Chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2H)-one
title_sort (z)-2-(4-chloro­benzyl­idene)benzo[d]thia­zolo[3,2-a]imidazol-3(2h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344520/
https://www.ncbi.nlm.nih.gov/pubmed/22590282
http://dx.doi.org/10.1107/S1600536812015516
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