rac-Methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate

In the racemic title compound, C(14)H(17)NO(6), the plane of the ester group of the methyl hexa­noate side chain makes a dihedral angle of 80.0 (2)° with the benzene ring, while the nitro group is approximately coplanar with the benzene ring [dihedral angle = 10.3 (2)°]. In the crystal, mol­ecules f...

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Detalles Bibliográficos
Autores principales: Song, Jun-Song, Wang, De-Cai, He, Xue-Jun, Qiu, Jiang-Kai, Ou-yang, Ping-Kai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344521/
https://www.ncbi.nlm.nih.gov/pubmed/22590283
http://dx.doi.org/10.1107/S1600536812015462
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author Song, Jun-Song
Wang, De-Cai
He, Xue-Jun
Qiu, Jiang-Kai
Ou-yang, Ping-Kai
author_facet Song, Jun-Song
Wang, De-Cai
He, Xue-Jun
Qiu, Jiang-Kai
Ou-yang, Ping-Kai
author_sort Song, Jun-Song
collection PubMed
description In the racemic title compound, C(14)H(17)NO(6), the plane of the ester group of the methyl hexa­noate side chain makes a dihedral angle of 80.0 (2)° with the benzene ring, while the nitro group is approximately coplanar with the benzene ring [dihedral angle = 10.3 (2)°]. In the crystal, mol­ecules form weak aromatic C—H⋯O(nitro) hydrogen-bonding inter­actions, giving inversion dimers [graph set R (2) (2)(8)].
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spelling pubmed-33445212012-05-15 rac-Methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate Song, Jun-Song Wang, De-Cai He, Xue-Jun Qiu, Jiang-Kai Ou-yang, Ping-Kai Acta Crystallogr Sect E Struct Rep Online Organic Papers In the racemic title compound, C(14)H(17)NO(6), the plane of the ester group of the methyl hexa­noate side chain makes a dihedral angle of 80.0 (2)° with the benzene ring, while the nitro group is approximately coplanar with the benzene ring [dihedral angle = 10.3 (2)°]. In the crystal, mol­ecules form weak aromatic C—H⋯O(nitro) hydrogen-bonding inter­actions, giving inversion dimers [graph set R (2) (2)(8)]. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344521/ /pubmed/22590283 http://dx.doi.org/10.1107/S1600536812015462 Text en © Song et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Song, Jun-Song
Wang, De-Cai
He, Xue-Jun
Qiu, Jiang-Kai
Ou-yang, Ping-Kai
rac-Methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate
title rac-Methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate
title_full rac-Methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate
title_fullStr rac-Methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate
title_full_unstemmed rac-Methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate
title_short rac-Methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate
title_sort rac-methyl 2-(2-formyl-4-nitro­phen­oxy)hexa­noate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344521/
https://www.ncbi.nlm.nih.gov/pubmed/22590283
http://dx.doi.org/10.1107/S1600536812015462
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