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4,4′-Dinitro-2,2′-[propane-1,3-diylbis(iminiumylmethanylylidene)]diphenolate
The title compound, C(17)H(16)N(4)O(6), is a Schiff base, which is found as a bis-zwitterion in the solid state. The geometry around the iminium N atom indicates sp (2)-hybridization. The diiminiumpropylene chain is in an approximate double-gauche conformation, with average N—C—C—C torsion angles o...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344525/ https://www.ncbi.nlm.nih.gov/pubmed/22590287 http://dx.doi.org/10.1107/S1600536812015504 |
Sumario: | The title compound, C(17)H(16)N(4)O(6), is a Schiff base, which is found as a bis-zwitterion in the solid state. The geometry around the iminium N atom indicates sp (2)-hybridization. The diiminiumpropylene chain is in an approximate double-gauche conformation, with average N—C—C—C torsion angles of 69.3°. The zwitterion shows strong intramolecular N—H⋯O hydrogen bonds between the iminium N and phenolate O atom. In the crystal, bifurcated N—H⋯(O,O) hydrogen bonds assemble pairs of molecules into inversion dimers. |
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