Ethyl (E)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2H-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate

In the title compound, C(28)H(27)NO(5)S, the five-membered pyrrolidine ring, which exhibits an envelope conformation (the C atom at the spiral junction being the flap atom), makes dihedral angles of 57.37 (10) and 86.84 (8)°, respectively, with the phenyl ring and the acenaphthyl­ene ring system. In...

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Detalles Bibliográficos
Autores principales: Sankar, Ulaganathan, Uma, R., Sundaramoorthy, S., Velmurugan, D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344527/
https://www.ncbi.nlm.nih.gov/pubmed/22590289
http://dx.doi.org/10.1107/S1600536812016042
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author Sankar, Ulaganathan
Uma, R.
Sundaramoorthy, S.
Velmurugan, D.
author_facet Sankar, Ulaganathan
Uma, R.
Sundaramoorthy, S.
Velmurugan, D.
author_sort Sankar, Ulaganathan
collection PubMed
description In the title compound, C(28)H(27)NO(5)S, the five-membered pyrrolidine ring, which exhibits an envelope conformation (the C atom at the spiral junction being the flap atom), makes dihedral angles of 57.37 (10) and 86.84 (8)°, respectively, with the phenyl ring and the acenaphthyl­ene ring system. In the crystal, mol­ecules associate via two C—H⋯O hydrogen bonds, forming R (2) (2)(20) and R (2) (2)(10) graph-set motifs.
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spelling pubmed-33445272012-05-15 Ethyl (E)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2H-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate Sankar, Ulaganathan Uma, R. Sundaramoorthy, S. Velmurugan, D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(27)NO(5)S, the five-membered pyrrolidine ring, which exhibits an envelope conformation (the C atom at the spiral junction being the flap atom), makes dihedral angles of 57.37 (10) and 86.84 (8)°, respectively, with the phenyl ring and the acenaphthyl­ene ring system. In the crystal, mol­ecules associate via two C—H⋯O hydrogen bonds, forming R (2) (2)(20) and R (2) (2)(10) graph-set motifs. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344527/ /pubmed/22590289 http://dx.doi.org/10.1107/S1600536812016042 Text en © Sankar et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sankar, Ulaganathan
Uma, R.
Sundaramoorthy, S.
Velmurugan, D.
Ethyl (E)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2H-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate
title Ethyl (E)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2H-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate
title_full Ethyl (E)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2H-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate
title_fullStr Ethyl (E)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2H-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate
title_full_unstemmed Ethyl (E)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2H-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate
title_short Ethyl (E)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2H-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate
title_sort ethyl (e)-3-[1′-ethyl-2-oxo-4′-(phenyl­sulfon­yl)-2h-spiro­[acenaphthyl­ene-1,2′-pyrrolidine]-3′-yl]acrylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344527/
https://www.ncbi.nlm.nih.gov/pubmed/22590289
http://dx.doi.org/10.1107/S1600536812016042
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AT sundaramoorthys ethyle31ethyl2oxo4phenylsulfonyl2hspiroacenaphthylene12pyrrolidine3ylacrylate
AT velmurugand ethyle31ethyl2oxo4phenylsulfonyl2hspiroacenaphthylene12pyrrolidine3ylacrylate

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