Benzyl 3-(2-methyl­phen­yl)dithio­carbazate

In the title compound, C(15)H(16)N(2)S(2), the central C(2)N(2)S(2) unit is essentially planar (r.m.s. deviation = 0.047 Å) and forms dihedral angles of 68.26 (4) and 65.99 (4)° with the phenyl and benzene rings, respectively, indicating a twisted mol­ecule. Supra­molecular chains with a step topolo...

Descripción completa

Detalles Bibliográficos
Autores principales: Tayamon, Shahedeh, Ravoof, Thahira Begum S. A., Tahir, Mohamed Ibrahim Mohamed, Crouse, Karen A., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344528/
https://www.ncbi.nlm.nih.gov/pubmed/22590290
http://dx.doi.org/10.1107/S160053681201567X
_version_ 1782232012118032384
author Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_facet Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_sort Tayamon, Shahedeh
collection PubMed
description In the title compound, C(15)H(16)N(2)S(2), the central C(2)N(2)S(2) unit is essentially planar (r.m.s. deviation = 0.047 Å) and forms dihedral angles of 68.26 (4) and 65.99 (4)° with the phenyl and benzene rings, respectively, indicating a twisted mol­ecule. Supra­molecular chains with a step topology and propagating along [100] feature in the crystal packing, mediated through N—H⋯S hydrogen bonds. The chains are consolidated into a three-dimensional architecture by C—H⋯π inter­actions.
format Online
Article
Text
id pubmed-3344528
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33445282012-05-15 Benzyl 3-(2-methyl­phen­yl)dithio­carbazate Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(16)N(2)S(2), the central C(2)N(2)S(2) unit is essentially planar (r.m.s. deviation = 0.047 Å) and forms dihedral angles of 68.26 (4) and 65.99 (4)° with the phenyl and benzene rings, respectively, indicating a twisted mol­ecule. Supra­molecular chains with a step topology and propagating along [100] feature in the crystal packing, mediated through N—H⋯S hydrogen bonds. The chains are consolidated into a three-dimensional architecture by C—H⋯π inter­actions. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344528/ /pubmed/22590290 http://dx.doi.org/10.1107/S160053681201567X Text en © Tayamon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
Benzyl 3-(2-methyl­phen­yl)dithio­carbazate
title Benzyl 3-(2-methyl­phen­yl)dithio­carbazate
title_full Benzyl 3-(2-methyl­phen­yl)dithio­carbazate
title_fullStr Benzyl 3-(2-methyl­phen­yl)dithio­carbazate
title_full_unstemmed Benzyl 3-(2-methyl­phen­yl)dithio­carbazate
title_short Benzyl 3-(2-methyl­phen­yl)dithio­carbazate
title_sort benzyl 3-(2-methyl­phen­yl)dithio­carbazate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344528/
https://www.ncbi.nlm.nih.gov/pubmed/22590290
http://dx.doi.org/10.1107/S160053681201567X
work_keys_str_mv AT tayamonshahedeh benzyl32methylphenyldithiocarbazate
AT ravoofthahirabegumsa benzyl32methylphenyldithiocarbazate
AT tahirmohamedibrahimmohamed benzyl32methylphenyldithiocarbazate
AT crousekarena benzyl32methylphenyldithiocarbazate
AT tiekinkedwardrt benzyl32methylphenyldithiocarbazate

Ejemplares similares