(R)-(3-Carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride

In the title salt (common name l-carnitine hydro­chloride), C(7)H(16)NO(3) (+)·Cl(−), the organic cation features a carb­oxy­lic part (–CO(2)H) having unambigous single- and double-bonds [1.336 (2), 1.211 (2) Å]. There is a large N—C—C bond angle [115.9 (1)°] for the C atom connected to the bulky tr...

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Autor principal: Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344540/
https://www.ncbi.nlm.nih.gov/pubmed/22590302
http://dx.doi.org/10.1107/S160053681201598X
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author Ng, Seik Weng
author_facet Ng, Seik Weng
author_sort Ng, Seik Weng
collection PubMed
description In the title salt (common name l-carnitine hydro­chloride), C(7)H(16)NO(3) (+)·Cl(−), the organic cation features a carb­oxy­lic part (–CO(2)H) having unambigous single- and double-bonds [1.336 (2), 1.211 (2) Å]. There is a large N—C—C bond angle [115.9 (1)°] for the C atom connected to the bulky trimethyl­amino substituent. In the crystal, the acid H atom forms a hydrogen bond to the chloride anion, whereas the hydroxyl H atom forms a longer hydrogen bond to the anion, generating a helical chain running along [001].
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spelling pubmed-33445402012-05-15 (R)-(3-Carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt (common name l-carnitine hydro­chloride), C(7)H(16)NO(3) (+)·Cl(−), the organic cation features a carb­oxy­lic part (–CO(2)H) having unambigous single- and double-bonds [1.336 (2), 1.211 (2) Å]. There is a large N—C—C bond angle [115.9 (1)°] for the C atom connected to the bulky trimethyl­amino substituent. In the crystal, the acid H atom forms a hydrogen bond to the chloride anion, whereas the hydroxyl H atom forms a longer hydrogen bond to the anion, generating a helical chain running along [001]. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344540/ /pubmed/22590302 http://dx.doi.org/10.1107/S160053681201598X Text en © Seik Weng Ng 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ng, Seik Weng
(R)-(3-Carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride
title (R)-(3-Carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride
title_full (R)-(3-Carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride
title_fullStr (R)-(3-Carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride
title_full_unstemmed (R)-(3-Carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride
title_short (R)-(3-Carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride
title_sort (r)-(3-carb­oxy-2-hy­droxy­prop­yl)tri­methyl­aza­nium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344540/
https://www.ncbi.nlm.nih.gov/pubmed/22590302
http://dx.doi.org/10.1107/S160053681201598X
work_keys_str_mv AT ngseikweng r3carboxy2hydroxypropyltrimethylazaniumchloride

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