Cargando…
N′-[(E)-4-Benzyloxy-2-hydroxybenzylidene]-4-nitrobenzohydrazide monohydrate
The title compound, C(21)H(17)N(3)O(5)·H(2)O, exists in the keto form with an E conformation with respect to the azomethine double bond. The twist angles between the aromatic rings are in the range 4.67 (10)–17.54 (10)°. A water molecule of solvation is present in the lattice. A conventional intra...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344544/ https://www.ncbi.nlm.nih.gov/pubmed/22590306 http://dx.doi.org/10.1107/S1600536812015401 |
Sumario: | The title compound, C(21)H(17)N(3)O(5)·H(2)O, exists in the keto form with an E conformation with respect to the azomethine double bond. The twist angles between the aromatic rings are in the range 4.67 (10)–17.54 (10)°. A water molecule of solvation is present in the lattice. A conventional intramolecular O—H⋯N hydrogen bond increases the rigidity of the molecule. Intermolecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bonding interactions establish a supramolecular linkage among the molecules in the crystal structure. There are also C—H⋯π interactions present. |
---|