N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate

The title compound, C(21)H(17)N(3)O(5)·H(2)O, exists in the keto form with an E conformation with respect to the azomethine double bond. The twist angles between the aromatic rings are in the range 4.67 (10)–17.54 (10)°. A water mol­ecule of solvation is present in the lattice. A conventional intra­...

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Detalles Bibliográficos
Autores principales: Joseph, Bibitha, Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344544/
https://www.ncbi.nlm.nih.gov/pubmed/22590306
http://dx.doi.org/10.1107/S1600536812015401
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author Joseph, Bibitha
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Joseph, Bibitha
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Joseph, Bibitha
collection PubMed
description The title compound, C(21)H(17)N(3)O(5)·H(2)O, exists in the keto form with an E conformation with respect to the azomethine double bond. The twist angles between the aromatic rings are in the range 4.67 (10)–17.54 (10)°. A water mol­ecule of solvation is present in the lattice. A conventional intra­molecular O—H⋯N hydrogen bond increases the rigidity of the mol­ecule. Inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bonding inter­actions establish a supra­molecular linkage among the mol­ecules in the crystal structure. There are also C—H⋯π inter­actions present.
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spelling pubmed-33445442012-05-15 N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate Joseph, Bibitha Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(17)N(3)O(5)·H(2)O, exists in the keto form with an E conformation with respect to the azomethine double bond. The twist angles between the aromatic rings are in the range 4.67 (10)–17.54 (10)°. A water mol­ecule of solvation is present in the lattice. A conventional intra­molecular O—H⋯N hydrogen bond increases the rigidity of the mol­ecule. Inter­molecular O—H⋯O, N—H⋯O and C—H⋯O hydrogen-bonding inter­actions establish a supra­molecular linkage among the mol­ecules in the crystal structure. There are also C—H⋯π inter­actions present. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344544/ /pubmed/22590306 http://dx.doi.org/10.1107/S1600536812015401 Text en © Joseph et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Joseph, Bibitha
Sithambaresan, M.
Kurup, M. R. Prathapachandra
N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_full N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_fullStr N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_full_unstemmed N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_short N′-[(E)-4-Benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_sort n′-[(e)-4-benz­yloxy-2-hy­droxy­benzyl­idene]-4-nitro­benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344544/
https://www.ncbi.nlm.nih.gov/pubmed/22590306
http://dx.doi.org/10.1107/S1600536812015401
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AT kurupmrprathapachandra ne4benzyloxy2hydroxybenzylidene4nitrobenzohydrazidemonohydrate

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