1,3-Diammonio-1,2,3-tride­oxy-cis-inositol sulfate

In the crystal structure of the title compound, C(6)H(16)N(2)O(3) (2+)·SO(4) (2−), each cation forms three O—H⋯O and five N—H⋯O hydrogen bonds to six neighbouring sulfate anions. In addition, interlinking of the cations by N—H⋯O interactions is also observed. The cyclo­hexane ring adopts a chair con...

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Detalles Bibliográficos
Autores principales: Neis, Christian, Merten, Günter J., Hegetschweiler, Kaspar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344546/
https://www.ncbi.nlm.nih.gov/pubmed/22590308
http://dx.doi.org/10.1107/S1600536812016029
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author Neis, Christian
Merten, Günter J.
Hegetschweiler, Kaspar
author_facet Neis, Christian
Merten, Günter J.
Hegetschweiler, Kaspar
author_sort Neis, Christian
collection PubMed
description In the crystal structure of the title compound, C(6)H(16)N(2)O(3) (2+)·SO(4) (2−), each cation forms three O—H⋯O and five N—H⋯O hydrogen bonds to six neighbouring sulfate anions. In addition, interlinking of the cations by N—H⋯O interactions is also observed. The cyclo­hexane ring adopts a chair conformation with two axial hy­droxy groups. Although the separation of 2.928 Å is almost ideal for a hydrogen bond, intra­molecular hydrogen bonding between these two hy­droxy groups is not observed.
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spelling pubmed-33445462012-05-15 1,3-Diammonio-1,2,3-tride­oxy-cis-inositol sulfate Neis, Christian Merten, Günter J. Hegetschweiler, Kaspar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(6)H(16)N(2)O(3) (2+)·SO(4) (2−), each cation forms three O—H⋯O and five N—H⋯O hydrogen bonds to six neighbouring sulfate anions. In addition, interlinking of the cations by N—H⋯O interactions is also observed. The cyclo­hexane ring adopts a chair conformation with two axial hy­droxy groups. Although the separation of 2.928 Å is almost ideal for a hydrogen bond, intra­molecular hydrogen bonding between these two hy­droxy groups is not observed. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344546/ /pubmed/22590308 http://dx.doi.org/10.1107/S1600536812016029 Text en © Neis et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Neis, Christian
Merten, Günter J.
Hegetschweiler, Kaspar
1,3-Diammonio-1,2,3-tride­oxy-cis-inositol sulfate
title 1,3-Diammonio-1,2,3-tride­oxy-cis-inositol sulfate
title_full 1,3-Diammonio-1,2,3-tride­oxy-cis-inositol sulfate
title_fullStr 1,3-Diammonio-1,2,3-tride­oxy-cis-inositol sulfate
title_full_unstemmed 1,3-Diammonio-1,2,3-tride­oxy-cis-inositol sulfate
title_short 1,3-Diammonio-1,2,3-tride­oxy-cis-inositol sulfate
title_sort 1,3-diammonio-1,2,3-tride­oxy-cis-inositol sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344546/
https://www.ncbi.nlm.nih.gov/pubmed/22590308
http://dx.doi.org/10.1107/S1600536812016029
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