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Dicyclohexylammonium hydrogen phenylphosphonate
In the title salt, [(C(6)H(11))(2)NH(2)](+)·[C(6)H(5)PO(2)(OH)](−), the anion is monodeprotonated and acts as both a hydrogen-bond donor and acceptor. The anions are linked by pairs of O—H⋯O interactions, forming inversion dimers with R (2) (2)(8) ring motifs. These dimers are bridged by two dicycl...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344552/ https://www.ncbi.nlm.nih.gov/pubmed/22590314 http://dx.doi.org/10.1107/S160053681201553X |
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author | Diop, Tidiane Diop, Libasse Maris, Thierry Stoeckli-Evans, Helen |
author_facet | Diop, Tidiane Diop, Libasse Maris, Thierry Stoeckli-Evans, Helen |
author_sort | Diop, Tidiane |
collection | PubMed |
description | In the title salt, [(C(6)H(11))(2)NH(2)](+)·[C(6)H(5)PO(2)(OH)](−), the anion is monodeprotonated and acts as both a hydrogen-bond donor and acceptor. The anions are linked by pairs of O—H⋯O interactions, forming inversion dimers with R (2) (2)(8) ring motifs. These dimers are bridged by two dicyclohexylaminium cations via pairs of N—H⋯O hydrogen bonds, giving R (4) (4)(12) ring motifs, forming chains propagating along [010]. The chains are bridged by C—H⋯O interactions, forming a two-dimensional network lying parallel to (101). |
format | Online Article Text |
id | pubmed-3344552 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33445522012-05-15 Dicyclohexylammonium hydrogen phenylphosphonate Diop, Tidiane Diop, Libasse Maris, Thierry Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, [(C(6)H(11))(2)NH(2)](+)·[C(6)H(5)PO(2)(OH)](−), the anion is monodeprotonated and acts as both a hydrogen-bond donor and acceptor. The anions are linked by pairs of O—H⋯O interactions, forming inversion dimers with R (2) (2)(8) ring motifs. These dimers are bridged by two dicyclohexylaminium cations via pairs of N—H⋯O hydrogen bonds, giving R (4) (4)(12) ring motifs, forming chains propagating along [010]. The chains are bridged by C—H⋯O interactions, forming a two-dimensional network lying parallel to (101). International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344552/ /pubmed/22590314 http://dx.doi.org/10.1107/S160053681201553X Text en © Diop et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Diop, Tidiane Diop, Libasse Maris, Thierry Stoeckli-Evans, Helen Dicyclohexylammonium hydrogen phenylphosphonate |
title | Dicyclohexylammonium hydrogen phenylphosphonate |
title_full | Dicyclohexylammonium hydrogen phenylphosphonate |
title_fullStr | Dicyclohexylammonium hydrogen phenylphosphonate |
title_full_unstemmed | Dicyclohexylammonium hydrogen phenylphosphonate |
title_short | Dicyclohexylammonium hydrogen phenylphosphonate |
title_sort | dicyclohexylammonium hydrogen phenylphosphonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344552/ https://www.ncbi.nlm.nih.gov/pubmed/22590314 http://dx.doi.org/10.1107/S160053681201553X |
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