4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one

In the title compound, C(21)H(23)NOS, the thia­zolidine ring adopts a twist conformation about one of its C—S bonds, while the cyclo­hexane ring has a chair conformation. The S and N atoms attached to the spiro C atom are in axial and equatorial orientations, respectively. The thia­zolidine ring for...

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Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Shanmugavelan, Poovan, Ponnuswamy, Alagusundaram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344557/
https://www.ncbi.nlm.nih.gov/pubmed/22590319
http://dx.doi.org/10.1107/S1600536812015358
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author Fun, Hoong-Kun
Chia, Tze Shyang
Shanmugavelan, Poovan
Ponnuswamy, Alagusundaram
author_facet Fun, Hoong-Kun
Chia, Tze Shyang
Shanmugavelan, Poovan
Ponnuswamy, Alagusundaram
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(21)H(23)NOS, the thia­zolidine ring adopts a twist conformation about one of its C—S bonds, while the cyclo­hexane ring has a chair conformation. The S and N atoms attached to the spiro C atom are in axial and equatorial orientations, respectively. The thia­zolidine ring forms dihedral angles of 86.24 (14) and 31.82 (15)° with the directly attached and remote terminal benzene rings, respectively. The dihedral angle between the two terminal benzene rings is 86.74 (14)°. In the crystal, the only significant directional inter­action is a weak C—H⋯π bond, which generates [010] chains.
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spelling pubmed-33445572012-05-15 4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one Fun, Hoong-Kun Chia, Tze Shyang Shanmugavelan, Poovan Ponnuswamy, Alagusundaram Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(23)NOS, the thia­zolidine ring adopts a twist conformation about one of its C—S bonds, while the cyclo­hexane ring has a chair conformation. The S and N atoms attached to the spiro C atom are in axial and equatorial orientations, respectively. The thia­zolidine ring forms dihedral angles of 86.24 (14) and 31.82 (15)° with the directly attached and remote terminal benzene rings, respectively. The dihedral angle between the two terminal benzene rings is 86.74 (14)°. In the crystal, the only significant directional inter­action is a weak C—H⋯π bond, which generates [010] chains. International Union of Crystallography 2012-04-18 /pmc/articles/PMC3344557/ /pubmed/22590319 http://dx.doi.org/10.1107/S1600536812015358 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chia, Tze Shyang
Shanmugavelan, Poovan
Ponnuswamy, Alagusundaram
4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one
title 4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one
title_full 4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one
title_fullStr 4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one
title_full_unstemmed 4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one
title_short 4-Benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one
title_sort 4-benzyl-8-phenyl-1-thia-4-aza­spiro­[4.5]decan-3-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344557/
https://www.ncbi.nlm.nih.gov/pubmed/22590319
http://dx.doi.org/10.1107/S1600536812015358
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