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3-Aminopyridin-1-ium 3-carboxybenzoate
In the title organic salt, C(5)H(7)N(2) (+)·C(8)H(5)O(4) (−), the carboxylic group is nearly coplanar with the benzene ring [dihedral angle 1.9 (4)°] whereas the carboxylate group is twisted relative to the benzene ring by 13.6 (4)°. In the crystal, N-H⋯O and O—H⋯O hydrogen bonds connect the comp...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344561/ https://www.ncbi.nlm.nih.gov/pubmed/22590323 http://dx.doi.org/10.1107/S1600536812016108 |
| _version_ | 1782232019716014080 |
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| author | Campos-Gaxiola, Jose J. Hernández-Ortega, Simón Morales-Morales, David Cruz Enríquez, Adriana |
| author_facet | Campos-Gaxiola, Jose J. Hernández-Ortega, Simón Morales-Morales, David Cruz Enríquez, Adriana |
| author_sort | Campos-Gaxiola, Jose J. |
| collection | PubMed |
| description | In the title organic salt, C(5)H(7)N(2) (+)·C(8)H(5)O(4) (−), the carboxylic group is nearly coplanar with the benzene ring [dihedral angle 1.9 (4)°] whereas the carboxylate group is twisted relative to the benzene ring by 13.6 (4)°. In the crystal, N-H⋯O and O—H⋯O hydrogen bonds connect the components into a three-dimensional framework consisting of stacks of alternating pairs of anions and cations exhibiting π–π stacking interactions with centroid–centroid distances in the range 3.676 (2)–3.711 (1) Å. The π–π stacks extend along [110] and [-110]. |
| format | Online Article Text |
| id | pubmed-3344561 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33445612012-05-15 3-Aminopyridin-1-ium 3-carboxybenzoate Campos-Gaxiola, Jose J. Hernández-Ortega, Simón Morales-Morales, David Cruz Enríquez, Adriana Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title organic salt, C(5)H(7)N(2) (+)·C(8)H(5)O(4) (−), the carboxylic group is nearly coplanar with the benzene ring [dihedral angle 1.9 (4)°] whereas the carboxylate group is twisted relative to the benzene ring by 13.6 (4)°. In the crystal, N-H⋯O and O—H⋯O hydrogen bonds connect the components into a three-dimensional framework consisting of stacks of alternating pairs of anions and cations exhibiting π–π stacking interactions with centroid–centroid distances in the range 3.676 (2)–3.711 (1) Å. The π–π stacks extend along [110] and [-110]. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344561/ /pubmed/22590323 http://dx.doi.org/10.1107/S1600536812016108 Text en © Campos-Gaxiola et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Campos-Gaxiola, Jose J. Hernández-Ortega, Simón Morales-Morales, David Cruz Enríquez, Adriana 3-Aminopyridin-1-ium 3-carboxybenzoate |
| title | 3-Aminopyridin-1-ium 3-carboxybenzoate |
| title_full | 3-Aminopyridin-1-ium 3-carboxybenzoate |
| title_fullStr | 3-Aminopyridin-1-ium 3-carboxybenzoate |
| title_full_unstemmed | 3-Aminopyridin-1-ium 3-carboxybenzoate |
| title_short | 3-Aminopyridin-1-ium 3-carboxybenzoate |
| title_sort | 3-aminopyridin-1-ium 3-carboxybenzoate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344561/ https://www.ncbi.nlm.nih.gov/pubmed/22590323 http://dx.doi.org/10.1107/S1600536812016108 |
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