3,11-Dibromo-14-(4-chloro­phen­yl)-14H-dibenzo[a,j]xanthene dimethyl­formamide monosolvate

In the title compound, C(27)H(15)Br(2)ClO·C(3)H(7)NO, the xanthene moiety has a flattened boat conformation with a folding angle between the naphthalene units of 9.46 (3)°. The mean planes of the xanthene system and its 4-chloro­phenyl substituent are nearly perpendicular [dihedral angle = 89.43 (5)...

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Detalles Bibliográficos
Autores principales: Song, Yong Bin, Liu, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344574/
https://www.ncbi.nlm.nih.gov/pubmed/22590336
http://dx.doi.org/10.1107/S1600536812016200
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author Song, Yong Bin
Liu, Bo
author_facet Song, Yong Bin
Liu, Bo
author_sort Song, Yong Bin
collection PubMed
description In the title compound, C(27)H(15)Br(2)ClO·C(3)H(7)NO, the xanthene moiety has a flattened boat conformation with a folding angle between the naphthalene units of 9.46 (3)°. The mean planes of the xanthene system and its 4-chloro­phenyl substituent are nearly perpendicular [dihedral angle = 89.43 (5)°]. The dimethyl­formamide solvent mol­ecule is disordered over two sets of sites with an occupancy ratio of 0.520 (11):0.480 (11).
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spelling pubmed-33445742012-05-15 3,11-Dibromo-14-(4-chloro­phen­yl)-14H-dibenzo[a,j]xanthene dimethyl­formamide monosolvate Song, Yong Bin Liu, Bo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(15)Br(2)ClO·C(3)H(7)NO, the xanthene moiety has a flattened boat conformation with a folding angle between the naphthalene units of 9.46 (3)°. The mean planes of the xanthene system and its 4-chloro­phenyl substituent are nearly perpendicular [dihedral angle = 89.43 (5)°]. The dimethyl­formamide solvent mol­ecule is disordered over two sets of sites with an occupancy ratio of 0.520 (11):0.480 (11). International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344574/ /pubmed/22590336 http://dx.doi.org/10.1107/S1600536812016200 Text en © Song and Liu 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Song, Yong Bin
Liu, Bo
3,11-Dibromo-14-(4-chloro­phen­yl)-14H-dibenzo[a,j]xanthene dimethyl­formamide monosolvate
title 3,11-Dibromo-14-(4-chloro­phen­yl)-14H-dibenzo[a,j]xanthene dimethyl­formamide monosolvate
title_full 3,11-Dibromo-14-(4-chloro­phen­yl)-14H-dibenzo[a,j]xanthene dimethyl­formamide monosolvate
title_fullStr 3,11-Dibromo-14-(4-chloro­phen­yl)-14H-dibenzo[a,j]xanthene dimethyl­formamide monosolvate
title_full_unstemmed 3,11-Dibromo-14-(4-chloro­phen­yl)-14H-dibenzo[a,j]xanthene dimethyl­formamide monosolvate
title_short 3,11-Dibromo-14-(4-chloro­phen­yl)-14H-dibenzo[a,j]xanthene dimethyl­formamide monosolvate
title_sort 3,11-dibromo-14-(4-chloro­phen­yl)-14h-dibenzo[a,j]xanthene dimethyl­formamide monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344574/
https://www.ncbi.nlm.nih.gov/pubmed/22590336
http://dx.doi.org/10.1107/S1600536812016200
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