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2,4,6-Tris(2,4-dimethylphenyl)-1,3,5-triazine
Two virtually superimposable molecules comprise the asymmetric unit of the title compound, C(27)H(27)N(3). The range of dihedral angles between the central 1,3,5-triazine ring and the attached benzene rings is 20.88 (14)–31.36 (14)°, and the shape of each molecule is of a flattened bowl. The cryst...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344576/ https://www.ncbi.nlm.nih.gov/pubmed/22590338 http://dx.doi.org/10.1107/S1600536812016261 |
Sumario: | Two virtually superimposable molecules comprise the asymmetric unit of the title compound, C(27)H(27)N(3). The range of dihedral angles between the central 1,3,5-triazine ring and the attached benzene rings is 20.88 (14)–31.36 (14)°, and the shape of each molecule is of a flattened bowl. The crystal packing features weak C—H⋯π bonds and π–π interactions between triazine and benzene rings [centroid–centroid separations = 3.7696 (17) and 3.7800 (18) Å] that result in the formation of supramolecular layers in the ac plane. The crystal studied was a non-merohedral twin with a minor twin component of 20.7 (3)%. |
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