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(2E)-1-(2,4-Dichloro­phen­yl)-3-(3,4,5-trimeth­oxy­phen­yl)prop-2-en-1-one

In the title compound, C(18)H(16)Cl(2)O(4), the dihedral angle between the benzene rings is 82.40 (4)°. The meth­oxy groups at both meta positions of the 3,4,5-trimeth­oxy­phenyl ring are slightly twisted from the aromatic ring [C—O—C—C = −166.60 (8) and −6.18 (13)°], whereas the meth­oxy group at t...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chia, Tze Shyang, Sapnakumari, M., Narayana, B., Sarojini, B. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344577/
https://www.ncbi.nlm.nih.gov/pubmed/22590339
http://dx.doi.org/10.1107/S1600536812016339
Descripción
Sumario:In the title compound, C(18)H(16)Cl(2)O(4), the dihedral angle between the benzene rings is 82.40 (4)°. The meth­oxy groups at both meta positions of the 3,4,5-trimeth­oxy­phenyl ring are slightly twisted from the aromatic ring [C—O—C—C = −166.60 (8) and −6.18 (13)°], whereas the meth­oxy group at the para position is almost perpendicular [C—O—C—C = 112.08 (9)°]. The ketone O atom is connected to the 2,4-dichloro­phenyl group through a C(ar)—C(ar)—C—O (ar = aromatic) torsion angle of −116.43 (9)°. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds into infinite chains along the b axis. The crystal structure also features C—H⋯π inter­actions.