3′,6′-Bis(diethyl­amino)-2-[(E)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate

In the title compound, C(38)H(42)N(4)O(4)·C(2)H(6)O, prepared via a spiro­lactam ring-formation reaction in a rhodamine dye, the xanthene ring system is approximately planar (r.m.s. deviation = 0.0014Å) and subtends dihedral angles of 88.10 (3) and 86.92 (4)° with the spiro­lactam (r.m.s. deviations...

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Detalles Bibliográficos
Autores principales: Wei, Zhen, Guo, Jinlong, Zheng, Xujun, Chen, Shunwei, Wan, Qun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344589/
https://www.ncbi.nlm.nih.gov/pubmed/22590351
http://dx.doi.org/10.1107/S1600536812016741
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author Wei, Zhen
Guo, Jinlong
Zheng, Xujun
Chen, Shunwei
Wan, Qun
author_facet Wei, Zhen
Guo, Jinlong
Zheng, Xujun
Chen, Shunwei
Wan, Qun
author_sort Wei, Zhen
collection PubMed
description In the title compound, C(38)H(42)N(4)O(4)·C(2)H(6)O, prepared via a spiro­lactam ring-formation reaction in a rhodamine dye, the xanthene ring system is approximately planar (r.m.s. deviation = 0.0014Å) and subtends dihedral angles of 88.10 (3) and 86.92 (4)° with the spiro­lactam (r.m.s. deviations = 0.0012 Å) and benzene rings, respectively. The crystal structure consists of chains parallel to [-101], formed via O—H⋯O inter­actions.
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spelling pubmed-33445892012-05-15 3′,6′-Bis(diethyl­amino)-2-[(E)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate Wei, Zhen Guo, Jinlong Zheng, Xujun Chen, Shunwei Wan, Qun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(38)H(42)N(4)O(4)·C(2)H(6)O, prepared via a spiro­lactam ring-formation reaction in a rhodamine dye, the xanthene ring system is approximately planar (r.m.s. deviation = 0.0014Å) and subtends dihedral angles of 88.10 (3) and 86.92 (4)° with the spiro­lactam (r.m.s. deviations = 0.0012 Å) and benzene rings, respectively. The crystal structure consists of chains parallel to [-101], formed via O—H⋯O inter­actions. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344589/ /pubmed/22590351 http://dx.doi.org/10.1107/S1600536812016741 Text en © Wei et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wei, Zhen
Guo, Jinlong
Zheng, Xujun
Chen, Shunwei
Wan, Qun
3′,6′-Bis(diethyl­amino)-2-[(E)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate
title 3′,6′-Bis(diethyl­amino)-2-[(E)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate
title_full 3′,6′-Bis(diethyl­amino)-2-[(E)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate
title_fullStr 3′,6′-Bis(diethyl­amino)-2-[(E)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate
title_full_unstemmed 3′,6′-Bis(diethyl­amino)-2-[(E)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate
title_short 3′,6′-Bis(diethyl­amino)-2-[(E)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate
title_sort 3′,6′-bis(diethyl­amino)-2-[(e)-2-(4-hy­droxy-3-meth­oxy­benzyl­idene­amino)­eth­yl]spiro­[isoindoline-1,9′-xanthen]-3-one ethanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344589/
https://www.ncbi.nlm.nih.gov/pubmed/22590351
http://dx.doi.org/10.1107/S1600536812016741
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