2,4,6,8-Tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one O-benzyl­oxime acetone monosolvate

In the title compound, C(38)H(31)Cl(4)N(3)O·C(3)H(6)O, the 3,7-diaza-bicycle exists in a chair–boat conformation. The 4-chloro­phenyl groups attached to the chair form are equatorially oriented at an angle of 18.15 (3)° with respect to each other, whereas the 4-chloro­phenyl groups attached to the b...

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Detalles Bibliográficos
Autores principales: Park, Dong Ho, Ramkumar, V., Parthiban, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344591/
https://www.ncbi.nlm.nih.gov/pubmed/22590353
http://dx.doi.org/10.1107/S1600536812016509
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author Park, Dong Ho
Ramkumar, V.
Parthiban, P.
author_facet Park, Dong Ho
Ramkumar, V.
Parthiban, P.
author_sort Park, Dong Ho
collection PubMed
description In the title compound, C(38)H(31)Cl(4)N(3)O·C(3)H(6)O, the 3,7-diaza-bicycle exists in a chair–boat conformation. The 4-chloro­phenyl groups attached to the chair form are equatorially oriented at an angle of 18.15 (3)° with respect to each other, whereas the 4-chloro­phenyl groups attached to the boat form are oriented at an angle of 32.64 (3)°. In the crystal, mol­ecules are linked by N—H⋯π and C—H⋯O inter­actions.
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spelling pubmed-33445912012-05-15 2,4,6,8-Tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one O-benzyl­oxime acetone monosolvate Park, Dong Ho Ramkumar, V. Parthiban, P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(38)H(31)Cl(4)N(3)O·C(3)H(6)O, the 3,7-diaza-bicycle exists in a chair–boat conformation. The 4-chloro­phenyl groups attached to the chair form are equatorially oriented at an angle of 18.15 (3)° with respect to each other, whereas the 4-chloro­phenyl groups attached to the boat form are oriented at an angle of 32.64 (3)°. In the crystal, mol­ecules are linked by N—H⋯π and C—H⋯O inter­actions. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344591/ /pubmed/22590353 http://dx.doi.org/10.1107/S1600536812016509 Text en © Park et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Park, Dong Ho
Ramkumar, V.
Parthiban, P.
2,4,6,8-Tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one O-benzyl­oxime acetone monosolvate
title 2,4,6,8-Tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one O-benzyl­oxime acetone monosolvate
title_full 2,4,6,8-Tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one O-benzyl­oxime acetone monosolvate
title_fullStr 2,4,6,8-Tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one O-benzyl­oxime acetone monosolvate
title_full_unstemmed 2,4,6,8-Tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one O-benzyl­oxime acetone monosolvate
title_short 2,4,6,8-Tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one O-benzyl­oxime acetone monosolvate
title_sort 2,4,6,8-tetra­kis(4-chloro­phen­yl)-3,7-diaza­bicyclo­[3.3.1]nonan-9-one o-benzyl­oxime acetone monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344591/
https://www.ncbi.nlm.nih.gov/pubmed/22590353
http://dx.doi.org/10.1107/S1600536812016509
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AT parthibanp 2468tetrakis4chlorophenyl37diazabicyclo331nonan9oneobenzyloximeacetonemonosolvate

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