1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea

The benzene rings of the biphenyl group in the title compound, C(20)H(14)ClN(3)O(3)S, are nearly coplanar [maximum deviation = 0.20 (3) Å]. The mean plane of the biphenyl group forms a dihedral angle of 5.24 (7)° with the aromatic ring of the nitro­chloro­benzene group. Intra­molecular N—H⋯Cl, N—H⋯O...

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Detalles Bibliográficos
Autores principales: Yusof, M. Sukeri M., Yamin, Bohari M., Ngah, Nurziana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344595/
https://www.ncbi.nlm.nih.gov/pubmed/22590357
http://dx.doi.org/10.1107/S1600536812016686
Descripción
Sumario:The benzene rings of the biphenyl group in the title compound, C(20)H(14)ClN(3)O(3)S, are nearly coplanar [maximum deviation = 0.20 (3) Å]. The mean plane of the biphenyl group forms a dihedral angle of 5.24 (7)° with the aromatic ring of the nitro­chloro­benzene group. Intra­molecular N—H⋯Cl, N—H⋯O and C—H⋯S hydrogen bonds stabilize the cis–trans conformation of the mol­ecule. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯S hydrogen bonds into mutually inter­woven corrugated layers parallel to (10-2).

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