1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea

The benzene rings of the biphenyl group in the title compound, C(20)H(14)ClN(3)O(3)S, are nearly coplanar [maximum deviation = 0.20 (3) Å]. The mean plane of the biphenyl group forms a dihedral angle of 5.24 (7)° with the aromatic ring of the nitro­chloro­benzene group. Intra­molecular N—H⋯Cl, N—H⋯O...

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Detalles Bibliográficos
Autores principales: Yusof, M. Sukeri M., Yamin, Bohari M., Ngah, Nurziana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344595/
https://www.ncbi.nlm.nih.gov/pubmed/22590357
http://dx.doi.org/10.1107/S1600536812016686
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author Yusof, M. Sukeri M.
Yamin, Bohari M.
Ngah, Nurziana
author_facet Yusof, M. Sukeri M.
Yamin, Bohari M.
Ngah, Nurziana
author_sort Yusof, M. Sukeri M.
collection PubMed
description The benzene rings of the biphenyl group in the title compound, C(20)H(14)ClN(3)O(3)S, are nearly coplanar [maximum deviation = 0.20 (3) Å]. The mean plane of the biphenyl group forms a dihedral angle of 5.24 (7)° with the aromatic ring of the nitro­chloro­benzene group. Intra­molecular N—H⋯Cl, N—H⋯O and C—H⋯S hydrogen bonds stabilize the cis–trans conformation of the mol­ecule. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯S hydrogen bonds into mutually inter­woven corrugated layers parallel to (10-2).
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spelling pubmed-33445952012-05-15 1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea Yusof, M. Sukeri M. Yamin, Bohari M. Ngah, Nurziana Acta Crystallogr Sect E Struct Rep Online Organic Papers The benzene rings of the biphenyl group in the title compound, C(20)H(14)ClN(3)O(3)S, are nearly coplanar [maximum deviation = 0.20 (3) Å]. The mean plane of the biphenyl group forms a dihedral angle of 5.24 (7)° with the aromatic ring of the nitro­chloro­benzene group. Intra­molecular N—H⋯Cl, N—H⋯O and C—H⋯S hydrogen bonds stabilize the cis–trans conformation of the mol­ecule. In the crystal, mol­ecules are linked by C—H⋯O and C—H⋯S hydrogen bonds into mutually inter­woven corrugated layers parallel to (10-2). International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344595/ /pubmed/22590357 http://dx.doi.org/10.1107/S1600536812016686 Text en © Yusof et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yusof, M. Sukeri M.
Yamin, Bohari M.
Ngah, Nurziana
1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea
title 1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea
title_full 1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea
title_fullStr 1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea
title_full_unstemmed 1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea
title_short 1-(Biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea
title_sort 1-(biphenyl-4-ylcarbon­yl)-3-(2-chloro-4-nitro­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344595/
https://www.ncbi.nlm.nih.gov/pubmed/22590357
http://dx.doi.org/10.1107/S1600536812016686
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AT ngahnurziana 1biphenyl4ylcarbonyl32chloro4nitrophenylthiourea

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