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4-Methylbenzoic acid–N′-[(E)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1)
In the title hydrated 1:1 adduct, C(8)H(8)O(2)·C(14)H(13)N(3)O·H(2)O, the Schiff base molecule exists in an E conformation with respect to the N=C bond [1.2843 (13) Å] and the dihedral angle between the pyridine ring and the benzene ring is 1.04 (5)°. In the crystal, molecules are linked by N—H⋯O,...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344602/ https://www.ncbi.nlm.nih.gov/pubmed/22590364 http://dx.doi.org/10.1107/S1600536812016868 |
| _version_ | 1782232029240229888 |
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| author | Fun, Hoong-Kun Ooi, Chin Wei Shetty, Divya N. Narayana, B. Sarojini, B. K. |
| author_facet | Fun, Hoong-Kun Ooi, Chin Wei Shetty, Divya N. Narayana, B. Sarojini, B. K. |
| author_sort | Fun, Hoong-Kun |
| collection | PubMed |
| description | In the title hydrated 1:1 adduct, C(8)H(8)O(2)·C(14)H(13)N(3)O·H(2)O, the Schiff base molecule exists in an E conformation with respect to the N=C bond [1.2843 (13) Å] and the dihedral angle between the pyridine ring and the benzene ring is 1.04 (5)°. In the crystal, molecules are linked by N—H⋯O, C—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds into sheets lying parallel to the ab plane. The crystal structure also features π–π interactions with centroid–centroid distances of 3.6224 (6) and 3.7121 (6) Å. |
| format | Online Article Text |
| id | pubmed-3344602 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33446022012-05-15 4-Methylbenzoic acid–N′-[(E)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1) Fun, Hoong-Kun Ooi, Chin Wei Shetty, Divya N. Narayana, B. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated 1:1 adduct, C(8)H(8)O(2)·C(14)H(13)N(3)O·H(2)O, the Schiff base molecule exists in an E conformation with respect to the N=C bond [1.2843 (13) Å] and the dihedral angle between the pyridine ring and the benzene ring is 1.04 (5)°. In the crystal, molecules are linked by N—H⋯O, C—H⋯O, O—H⋯O and O—H⋯N hydrogen bonds into sheets lying parallel to the ab plane. The crystal structure also features π–π interactions with centroid–centroid distances of 3.6224 (6) and 3.7121 (6) Å. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344602/ /pubmed/22590364 http://dx.doi.org/10.1107/S1600536812016868 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Fun, Hoong-Kun Ooi, Chin Wei Shetty, Divya N. Narayana, B. Sarojini, B. K. 4-Methylbenzoic acid–N′-[(E)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1) |
| title | 4-Methylbenzoic acid–N′-[(E)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1) |
| title_full | 4-Methylbenzoic acid–N′-[(E)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1) |
| title_fullStr | 4-Methylbenzoic acid–N′-[(E)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1) |
| title_full_unstemmed | 4-Methylbenzoic acid–N′-[(E)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1) |
| title_short | 4-Methylbenzoic acid–N′-[(E)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1) |
| title_sort | 4-methylbenzoic acid–n′-[(e)-4-methylbenzylidene]pyridine-4-carbohydrazide–water (1/1/1) |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344602/ https://www.ncbi.nlm.nih.gov/pubmed/22590364 http://dx.doi.org/10.1107/S1600536812016868 |
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