Cargando…

2-Amino-3-carb­oxy­pyridinium chloride hemihydrate

The asymmetric unit of the title compound, C(6)H(7)N(2)O(2) (+)·Cl(−)·0.5H(2)O, consists of two protonated 2-amino-3-carb­oxy­pyridine cations, two chloride anions and one mol­ecule of water. The crystal packing can be described as alternating layers of cations and anions parallel to (110), which ar...

Descripción completa

Detalles Bibliográficos
Autores principales: Bouchene, Rafika, Bouacida, Sofiane, Berrah, Fadila, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344603/
https://www.ncbi.nlm.nih.gov/pubmed/22590365
http://dx.doi.org/10.1107/S1600536812017230
_version_ 1782232029469868032
author Bouchene, Rafika
Bouacida, Sofiane
Berrah, Fadila
Daran, Jean-Claude
author_facet Bouchene, Rafika
Bouacida, Sofiane
Berrah, Fadila
Daran, Jean-Claude
author_sort Bouchene, Rafika
collection PubMed
description The asymmetric unit of the title compound, C(6)H(7)N(2)O(2) (+)·Cl(−)·0.5H(2)O, consists of two protonated 2-amino-3-carb­oxy­pyridine cations, two chloride anions and one mol­ecule of water. The crystal packing can be described as alternating layers of cations and anions parallel to (110), which are linked together by O(w)—H⋯Cl inter­actions. In the crystal, four types of classical hydrogen bonds are observed, viz. cation–anion (O—H⋯Cl and N—H⋯Cl), cation–cation (N—H⋯O), cation–water (N—H⋯O(w)) and water–anion (O(w)—H⋯Cl), resulting in the formation of an infinite three-dimensional network.
format Online
Article
Text
id pubmed-3344603
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33446032012-05-15 2-Amino-3-carb­oxy­pyridinium chloride hemihydrate Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(6)H(7)N(2)O(2) (+)·Cl(−)·0.5H(2)O, consists of two protonated 2-amino-3-carb­oxy­pyridine cations, two chloride anions and one mol­ecule of water. The crystal packing can be described as alternating layers of cations and anions parallel to (110), which are linked together by O(w)—H⋯Cl inter­actions. In the crystal, four types of classical hydrogen bonds are observed, viz. cation–anion (O—H⋯Cl and N—H⋯Cl), cation–cation (N—H⋯O), cation–water (N—H⋯O(w)) and water–anion (O(w)—H⋯Cl), resulting in the formation of an infinite three-dimensional network. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344603/ /pubmed/22590365 http://dx.doi.org/10.1107/S1600536812017230 Text en © Bouchene et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bouchene, Rafika
Bouacida, Sofiane
Berrah, Fadila
Daran, Jean-Claude
2-Amino-3-carb­oxy­pyridinium chloride hemihydrate
title 2-Amino-3-carb­oxy­pyridinium chloride hemihydrate
title_full 2-Amino-3-carb­oxy­pyridinium chloride hemihydrate
title_fullStr 2-Amino-3-carb­oxy­pyridinium chloride hemihydrate
title_full_unstemmed 2-Amino-3-carb­oxy­pyridinium chloride hemihydrate
title_short 2-Amino-3-carb­oxy­pyridinium chloride hemihydrate
title_sort 2-amino-3-carb­oxy­pyridinium chloride hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344603/
https://www.ncbi.nlm.nih.gov/pubmed/22590365
http://dx.doi.org/10.1107/S1600536812017230
work_keys_str_mv AT bouchenerafika 2amino3carboxypyridiniumchloridehemihydrate
AT bouacidasofiane 2amino3carboxypyridiniumchloridehemihydrate
AT berrahfadila 2amino3carboxypyridiniumchloridehemihydrate
AT daranjeanclaude 2amino3carboxypyridiniumchloridehemihydrate