Cargando…
2-Amino-3-carboxypyridinium chloride hemihydrate
The asymmetric unit of the title compound, C(6)H(7)N(2)O(2) (+)·Cl(−)·0.5H(2)O, consists of two protonated 2-amino-3-carboxypyridine cations, two chloride anions and one molecule of water. The crystal packing can be described as alternating layers of cations and anions parallel to (110), which ar...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344603/ https://www.ncbi.nlm.nih.gov/pubmed/22590365 http://dx.doi.org/10.1107/S1600536812017230 |
_version_ | 1782232029469868032 |
---|---|
author | Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Daran, Jean-Claude |
author_facet | Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Daran, Jean-Claude |
author_sort | Bouchene, Rafika |
collection | PubMed |
description | The asymmetric unit of the title compound, C(6)H(7)N(2)O(2) (+)·Cl(−)·0.5H(2)O, consists of two protonated 2-amino-3-carboxypyridine cations, two chloride anions and one molecule of water. The crystal packing can be described as alternating layers of cations and anions parallel to (110), which are linked together by O(w)—H⋯Cl interactions. In the crystal, four types of classical hydrogen bonds are observed, viz. cation–anion (O—H⋯Cl and N—H⋯Cl), cation–cation (N—H⋯O), cation–water (N—H⋯O(w)) and water–anion (O(w)—H⋯Cl), resulting in the formation of an infinite three-dimensional network. |
format | Online Article Text |
id | pubmed-3344603 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33446032012-05-15 2-Amino-3-carboxypyridinium chloride hemihydrate Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(6)H(7)N(2)O(2) (+)·Cl(−)·0.5H(2)O, consists of two protonated 2-amino-3-carboxypyridine cations, two chloride anions and one molecule of water. The crystal packing can be described as alternating layers of cations and anions parallel to (110), which are linked together by O(w)—H⋯Cl interactions. In the crystal, four types of classical hydrogen bonds are observed, viz. cation–anion (O—H⋯Cl and N—H⋯Cl), cation–cation (N—H⋯O), cation–water (N—H⋯O(w)) and water–anion (O(w)—H⋯Cl), resulting in the formation of an infinite three-dimensional network. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344603/ /pubmed/22590365 http://dx.doi.org/10.1107/S1600536812017230 Text en © Bouchene et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bouchene, Rafika Bouacida, Sofiane Berrah, Fadila Daran, Jean-Claude 2-Amino-3-carboxypyridinium chloride hemihydrate |
title | 2-Amino-3-carboxypyridinium chloride hemihydrate |
title_full | 2-Amino-3-carboxypyridinium chloride hemihydrate |
title_fullStr | 2-Amino-3-carboxypyridinium chloride hemihydrate |
title_full_unstemmed | 2-Amino-3-carboxypyridinium chloride hemihydrate |
title_short | 2-Amino-3-carboxypyridinium chloride hemihydrate |
title_sort | 2-amino-3-carboxypyridinium chloride hemihydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344603/ https://www.ncbi.nlm.nih.gov/pubmed/22590365 http://dx.doi.org/10.1107/S1600536812017230 |
work_keys_str_mv | AT bouchenerafika 2amino3carboxypyridiniumchloridehemihydrate AT bouacidasofiane 2amino3carboxypyridiniumchloridehemihydrate AT berrahfadila 2amino3carboxypyridiniumchloridehemihydrate AT daranjeanclaude 2amino3carboxypyridiniumchloridehemihydrate |