Cargando…
2,4-Diiodo-3-nitroanisole
In the title compound (systematic name: 1,3-diiodo-4-methoxy-2-nitrobenzene), C(7)H(5)I(2)NO(3), the dihedral angle between the benzene ring and the nitro group is 88.0 (3)°, and the methyl group lies almost in the same plane as the ring [deviation = 0.034 (6) Å]. In the crystal, aromatic π–π stac...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344609/ https://www.ncbi.nlm.nih.gov/pubmed/22590371 http://dx.doi.org/10.1107/S160053681200952X |
_version_ | 1782232030836162560 |
---|---|
author | Li, Xianfei Cao, Lei Ruan, Chuansheng Ji, Baoming Zhou, Le |
author_facet | Li, Xianfei Cao, Lei Ruan, Chuansheng Ji, Baoming Zhou, Le |
author_sort | Li, Xianfei |
collection | PubMed |
description | In the title compound (systematic name: 1,3-diiodo-4-methoxy-2-nitrobenzene), C(7)H(5)I(2)NO(3), the dihedral angle between the benzene ring and the nitro group is 88.0 (3)°, and the methyl group lies almost in the same plane as the ring [deviation = 0.034 (6) Å]. In the crystal, aromatic π–π stacking occurs between inversion-related rings [centroid–centroid separation = 3.865 (3) Å and slippage = 0.642 Å]. A possible weak C—I⋯π interaction occurs [I⋯π = 3.701 (2) Å and C—I⋯π = 130.18 (13)°], but there are no significant intermolecular I⋯I contacts. |
format | Online Article Text |
id | pubmed-3344609 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33446092012-05-15 2,4-Diiodo-3-nitroanisole Li, Xianfei Cao, Lei Ruan, Chuansheng Ji, Baoming Zhou, Le Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound (systematic name: 1,3-diiodo-4-methoxy-2-nitrobenzene), C(7)H(5)I(2)NO(3), the dihedral angle between the benzene ring and the nitro group is 88.0 (3)°, and the methyl group lies almost in the same plane as the ring [deviation = 0.034 (6) Å]. In the crystal, aromatic π–π stacking occurs between inversion-related rings [centroid–centroid separation = 3.865 (3) Å and slippage = 0.642 Å]. A possible weak C—I⋯π interaction occurs [I⋯π = 3.701 (2) Å and C—I⋯π = 130.18 (13)°], but there are no significant intermolecular I⋯I contacts. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344609/ /pubmed/22590371 http://dx.doi.org/10.1107/S160053681200952X Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Xianfei Cao, Lei Ruan, Chuansheng Ji, Baoming Zhou, Le 2,4-Diiodo-3-nitroanisole |
title | 2,4-Diiodo-3-nitroanisole |
title_full | 2,4-Diiodo-3-nitroanisole |
title_fullStr | 2,4-Diiodo-3-nitroanisole |
title_full_unstemmed | 2,4-Diiodo-3-nitroanisole |
title_short | 2,4-Diiodo-3-nitroanisole |
title_sort | 2,4-diiodo-3-nitroanisole |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344609/ https://www.ncbi.nlm.nih.gov/pubmed/22590371 http://dx.doi.org/10.1107/S160053681200952X |
work_keys_str_mv | AT lixianfei 24diiodo3nitroanisole AT caolei 24diiodo3nitroanisole AT ruanchuansheng 24diiodo3nitroanisole AT jibaoming 24diiodo3nitroanisole AT zhoule 24diiodo3nitroanisole |