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2,4-Diiodo-3-nitro­anisole

In the title compound (systematic name: 1,3-diiodo-4-meth­oxy-2-nitro­benzene), C(7)H(5)I(2)NO(3), the dihedral angle between the benzene ring and the nitro group is 88.0 (3)°, and the methyl group lies almost in the same plane as the ring [deviation = 0.034 (6) Å]. In the crystal, aromatic π–π stac...

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Detalles Bibliográficos
Autores principales: Li, Xianfei, Cao, Lei, Ruan, Chuansheng, Ji, Baoming, Zhou, Le
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344609/
https://www.ncbi.nlm.nih.gov/pubmed/22590371
http://dx.doi.org/10.1107/S160053681200952X
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author Li, Xianfei
Cao, Lei
Ruan, Chuansheng
Ji, Baoming
Zhou, Le
author_facet Li, Xianfei
Cao, Lei
Ruan, Chuansheng
Ji, Baoming
Zhou, Le
author_sort Li, Xianfei
collection PubMed
description In the title compound (systematic name: 1,3-diiodo-4-meth­oxy-2-nitro­benzene), C(7)H(5)I(2)NO(3), the dihedral angle between the benzene ring and the nitro group is 88.0 (3)°, and the methyl group lies almost in the same plane as the ring [deviation = 0.034 (6) Å]. In the crystal, aromatic π–π stacking occurs between inversion-related rings [centroid–centroid separation = 3.865 (3) Å and slippage = 0.642 Å]. A possible weak C—I⋯π inter­action occurs [I⋯π = 3.701 (2) Å and C—I⋯π = 130.18 (13)°], but there are no significant inter­molecular I⋯I contacts.
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spelling pubmed-33446092012-05-15 2,4-Diiodo-3-nitro­anisole Li, Xianfei Cao, Lei Ruan, Chuansheng Ji, Baoming Zhou, Le Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound (systematic name: 1,3-diiodo-4-meth­oxy-2-nitro­benzene), C(7)H(5)I(2)NO(3), the dihedral angle between the benzene ring and the nitro group is 88.0 (3)°, and the methyl group lies almost in the same plane as the ring [deviation = 0.034 (6) Å]. In the crystal, aromatic π–π stacking occurs between inversion-related rings [centroid–centroid separation = 3.865 (3) Å and slippage = 0.642 Å]. A possible weak C—I⋯π inter­action occurs [I⋯π = 3.701 (2) Å and C—I⋯π = 130.18 (13)°], but there are no significant inter­molecular I⋯I contacts. International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344609/ /pubmed/22590371 http://dx.doi.org/10.1107/S160053681200952X Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Xianfei
Cao, Lei
Ruan, Chuansheng
Ji, Baoming
Zhou, Le
2,4-Diiodo-3-nitro­anisole
title 2,4-Diiodo-3-nitro­anisole
title_full 2,4-Diiodo-3-nitro­anisole
title_fullStr 2,4-Diiodo-3-nitro­anisole
title_full_unstemmed 2,4-Diiodo-3-nitro­anisole
title_short 2,4-Diiodo-3-nitro­anisole
title_sort 2,4-diiodo-3-nitro­anisole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344609/
https://www.ncbi.nlm.nih.gov/pubmed/22590371
http://dx.doi.org/10.1107/S160053681200952X
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