(E)-1-(2,4-Dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one

In the title compound, C(21)H(19)NO, there are two mol­ecules in the asymmetric unit (Z′ = 2). There are π–π inter­actions between these two mol­ecules [centroid–centroid distance = 3.678 (2) Å], as well as a weak C—H⋯O inter­action. The conformation adopted by the two mol­ecules is such that the qu...

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Detalles Bibliográficos
Autores principales: Prasath, R., Bhavana, P., Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344610/
https://www.ncbi.nlm.nih.gov/pubmed/22590372
http://dx.doi.org/10.1107/S1600536812015498
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author Prasath, R.
Bhavana, P.
Butcher, Ray J.
author_facet Prasath, R.
Bhavana, P.
Butcher, Ray J.
author_sort Prasath, R.
collection PubMed
description In the title compound, C(21)H(19)NO, there are two mol­ecules in the asymmetric unit (Z′ = 2). There are π–π inter­actions between these two mol­ecules [centroid–centroid distance = 3.678 (2) Å], as well as a weak C—H⋯O inter­action. The conformation adopted by the two mol­ecules is such that the quinoline mean plane and the benzene ring are almost perpendicular [89.04 (5) and 76.89 (4)°]. In each mol­ecule, the methyl group of the tolyl ring is disordered over two conformations, with occupancy ratios of 0.56 (3):0.44 (3) and 0.65 (3):0.35 (3).
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spelling pubmed-33446102012-05-15 (E)-1-(2,4-Dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one Prasath, R. Bhavana, P. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(19)NO, there are two mol­ecules in the asymmetric unit (Z′ = 2). There are π–π inter­actions between these two mol­ecules [centroid–centroid distance = 3.678 (2) Å], as well as a weak C—H⋯O inter­action. The conformation adopted by the two mol­ecules is such that the quinoline mean plane and the benzene ring are almost perpendicular [89.04 (5) and 76.89 (4)°]. In each mol­ecule, the methyl group of the tolyl ring is disordered over two conformations, with occupancy ratios of 0.56 (3):0.44 (3) and 0.65 (3):0.35 (3). International Union of Crystallography 2012-04-21 /pmc/articles/PMC3344610/ /pubmed/22590372 http://dx.doi.org/10.1107/S1600536812015498 Text en © Prasath et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prasath, R.
Bhavana, P.
Butcher, Ray J.
(E)-1-(2,4-Dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one
title (E)-1-(2,4-Dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one
title_full (E)-1-(2,4-Dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one
title_fullStr (E)-1-(2,4-Dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one
title_full_unstemmed (E)-1-(2,4-Dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one
title_short (E)-1-(2,4-Dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one
title_sort (e)-1-(2,4-dimethyl­quinolin-3-yl)-3-(4-methyl­phen­yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344610/
https://www.ncbi.nlm.nih.gov/pubmed/22590372
http://dx.doi.org/10.1107/S1600536812015498
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AT bhavanap e124dimethylquinolin3yl34methylphenylprop2en1one
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