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(Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine

In the asymmetric unit of the title compound, C(16)H(12)BrN(7)S, there are two crystallographically independent mol­ecules with similar conformations. Both mol­ecules are slightly twisted; the central 1,2,4-triazolo[3,4-b]-1,3,4-thia­diazine ring system makes dihedral angles of 9.65 (15) and 13.29 (...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Bhat, Mashooq A., Abdel-Aziz, Hatem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344618/
https://www.ncbi.nlm.nih.gov/pubmed/22590380
http://dx.doi.org/10.1107/S1600536812017412
Descripción
Sumario:In the asymmetric unit of the title compound, C(16)H(12)BrN(7)S, there are two crystallographically independent mol­ecules with similar conformations. Both mol­ecules are slightly twisted; the central 1,2,4-triazolo[3,4-b]-1,3,4-thia­diazine ring system makes dihedral angles of 9.65 (15) and 13.29 (15)° with the pyridine and benzene rings, respectively, in one mol­ecule, whereas the corresponding values in the other mol­ecule are 9.30 (15) and 4.84 (15)°. A weak intra­molecular C—H⋯N inter­action with an S(6) ring motif is observed in each mol­ecule. In the crystal, the independent mol­ecules are each linked through N—H⋯N hydrogen bonds and weak C—H⋯N interactions into ribbons along the c axis. The ribbons are further linked together by weak C—H⋯N, C—H⋯π and π–π [centroid–centroid distances = 3.572 (2)–3.884 (2) Å] inter­actions.