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(Z)-7-[2-(4-Bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine
In the asymmetric unit of the title compound, C(16)H(12)BrN(7)S, there are two crystallographically independent molecules with similar conformations. Both molecules are slightly twisted; the central 1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine ring system makes dihedral angles of 9.65 (15) and 13.29 (...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344618/ https://www.ncbi.nlm.nih.gov/pubmed/22590380 http://dx.doi.org/10.1107/S1600536812017412 |
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author | Fun, Hoong-Kun Chantrapromma, Suchada Bhat, Mashooq A. Abdel-Aziz, Hatem A. |
author_facet | Fun, Hoong-Kun Chantrapromma, Suchada Bhat, Mashooq A. Abdel-Aziz, Hatem A. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the asymmetric unit of the title compound, C(16)H(12)BrN(7)S, there are two crystallographically independent molecules with similar conformations. Both molecules are slightly twisted; the central 1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine ring system makes dihedral angles of 9.65 (15) and 13.29 (15)° with the pyridine and benzene rings, respectively, in one molecule, whereas the corresponding values in the other molecule are 9.30 (15) and 4.84 (15)°. A weak intramolecular C—H⋯N interaction with an S(6) ring motif is observed in each molecule. In the crystal, the independent molecules are each linked through N—H⋯N hydrogen bonds and weak C—H⋯N interactions into ribbons along the c axis. The ribbons are further linked together by weak C—H⋯N, C—H⋯π and π–π [centroid–centroid distances = 3.572 (2)–3.884 (2) Å] interactions. |
format | Online Article Text |
id | pubmed-3344618 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33446182012-05-15 (Z)-7-[2-(4-Bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine Fun, Hoong-Kun Chantrapromma, Suchada Bhat, Mashooq A. Abdel-Aziz, Hatem A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, C(16)H(12)BrN(7)S, there are two crystallographically independent molecules with similar conformations. Both molecules are slightly twisted; the central 1,2,4-triazolo[3,4-b]-1,3,4-thiadiazine ring system makes dihedral angles of 9.65 (15) and 13.29 (15)° with the pyridine and benzene rings, respectively, in one molecule, whereas the corresponding values in the other molecule are 9.30 (15) and 4.84 (15)°. A weak intramolecular C—H⋯N interaction with an S(6) ring motif is observed in each molecule. In the crystal, the independent molecules are each linked through N—H⋯N hydrogen bonds and weak C—H⋯N interactions into ribbons along the c axis. The ribbons are further linked together by weak C—H⋯N, C—H⋯π and π–π [centroid–centroid distances = 3.572 (2)–3.884 (2) Å] interactions. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344618/ /pubmed/22590380 http://dx.doi.org/10.1107/S1600536812017412 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chantrapromma, Suchada Bhat, Mashooq A. Abdel-Aziz, Hatem A. (Z)-7-[2-(4-Bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine |
title | (Z)-7-[2-(4-Bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine |
title_full | (Z)-7-[2-(4-Bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine |
title_fullStr | (Z)-7-[2-(4-Bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine |
title_full_unstemmed | (Z)-7-[2-(4-Bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine |
title_short | (Z)-7-[2-(4-Bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine |
title_sort | (z)-7-[2-(4-bromophenyl)hydrazin-1-ylidene]-6-methyl-3-(pyridin-4-yl)-7h-1,2,4-triazolo[3,4-b][1,3,4]thiadiazine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344618/ https://www.ncbi.nlm.nih.gov/pubmed/22590380 http://dx.doi.org/10.1107/S1600536812017412 |
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