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(Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine

In the asymmetric unit of the title compound, C(16)H(12)BrN(7)S, there are two crystallographically independent mol­ecules with similar conformations. Both mol­ecules are slightly twisted; the central 1,2,4-triazolo[3,4-b]-1,3,4-thia­diazine ring system makes dihedral angles of 9.65 (15) and 13.29 (...

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Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Bhat, Mashooq A., Abdel-Aziz, Hatem A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344618/
https://www.ncbi.nlm.nih.gov/pubmed/22590380
http://dx.doi.org/10.1107/S1600536812017412
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author Fun, Hoong-Kun
Chantrapromma, Suchada
Bhat, Mashooq A.
Abdel-Aziz, Hatem A.
author_facet Fun, Hoong-Kun
Chantrapromma, Suchada
Bhat, Mashooq A.
Abdel-Aziz, Hatem A.
author_sort Fun, Hoong-Kun
collection PubMed
description In the asymmetric unit of the title compound, C(16)H(12)BrN(7)S, there are two crystallographically independent mol­ecules with similar conformations. Both mol­ecules are slightly twisted; the central 1,2,4-triazolo[3,4-b]-1,3,4-thia­diazine ring system makes dihedral angles of 9.65 (15) and 13.29 (15)° with the pyridine and benzene rings, respectively, in one mol­ecule, whereas the corresponding values in the other mol­ecule are 9.30 (15) and 4.84 (15)°. A weak intra­molecular C—H⋯N inter­action with an S(6) ring motif is observed in each mol­ecule. In the crystal, the independent mol­ecules are each linked through N—H⋯N hydrogen bonds and weak C—H⋯N interactions into ribbons along the c axis. The ribbons are further linked together by weak C—H⋯N, C—H⋯π and π–π [centroid–centroid distances = 3.572 (2)–3.884 (2) Å] inter­actions.
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spelling pubmed-33446182012-05-15 (Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine Fun, Hoong-Kun Chantrapromma, Suchada Bhat, Mashooq A. Abdel-Aziz, Hatem A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the asymmetric unit of the title compound, C(16)H(12)BrN(7)S, there are two crystallographically independent mol­ecules with similar conformations. Both mol­ecules are slightly twisted; the central 1,2,4-triazolo[3,4-b]-1,3,4-thia­diazine ring system makes dihedral angles of 9.65 (15) and 13.29 (15)° with the pyridine and benzene rings, respectively, in one mol­ecule, whereas the corresponding values in the other mol­ecule are 9.30 (15) and 4.84 (15)°. A weak intra­molecular C—H⋯N inter­action with an S(6) ring motif is observed in each mol­ecule. In the crystal, the independent mol­ecules are each linked through N—H⋯N hydrogen bonds and weak C—H⋯N interactions into ribbons along the c axis. The ribbons are further linked together by weak C—H⋯N, C—H⋯π and π–π [centroid–centroid distances = 3.572 (2)–3.884 (2) Å] inter­actions. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344618/ /pubmed/22590380 http://dx.doi.org/10.1107/S1600536812017412 Text en © Fun et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chantrapromma, Suchada
Bhat, Mashooq A.
Abdel-Aziz, Hatem A.
(Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine
title (Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine
title_full (Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine
title_fullStr (Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine
title_full_unstemmed (Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine
title_short (Z)-7-[2-(4-Bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7H-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine
title_sort (z)-7-[2-(4-bromo­phen­yl)hydrazin-1-yl­idene]-6-methyl-3-(pyridin-4-yl)-7h-1,2,4-triazolo[3,4-b][1,3,4]thia­diazine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344618/
https://www.ncbi.nlm.nih.gov/pubmed/22590380
http://dx.doi.org/10.1107/S1600536812017412
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