1,4-Dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate

In the title hydrated mol­ecular salt, C(6)H(16)N(2) (+)·2PF(6) (−)·2H(2)O, the complete 1,4-dimethyl­piperazine-1,4-diium dication is generated by crystallographic inversion symmetry and both C—N bonds are in equatorial orientations. In the crystal, the components are linked by O—H⋯F and N—H⋯O hydr...

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Autor principal: Sun, Su-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344619/
https://www.ncbi.nlm.nih.gov/pubmed/22590381
http://dx.doi.org/10.1107/S1600536812017229
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author Sun, Su-Wen
author_facet Sun, Su-Wen
author_sort Sun, Su-Wen
collection PubMed
description In the title hydrated mol­ecular salt, C(6)H(16)N(2) (+)·2PF(6) (−)·2H(2)O, the complete 1,4-dimethyl­piperazine-1,4-diium dication is generated by crystallographic inversion symmetry and both C—N bonds are in equatorial orientations. In the crystal, the components are linked by O—H⋯F and N—H⋯O hydrogen bonds but there are no direct links between cations and anions.
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spelling pubmed-33446192012-05-15 1,4-Dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate Sun, Su-Wen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated mol­ecular salt, C(6)H(16)N(2) (+)·2PF(6) (−)·2H(2)O, the complete 1,4-dimethyl­piperazine-1,4-diium dication is generated by crystallographic inversion symmetry and both C—N bonds are in equatorial orientations. In the crystal, the components are linked by O—H⋯F and N—H⋯O hydrogen bonds but there are no direct links between cations and anions. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344619/ /pubmed/22590381 http://dx.doi.org/10.1107/S1600536812017229 Text en © Su-Wen Sun 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Su-Wen
1,4-Dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate
title 1,4-Dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate
title_full 1,4-Dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate
title_fullStr 1,4-Dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate
title_full_unstemmed 1,4-Dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate
title_short 1,4-Dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate
title_sort 1,4-dimethyl­piperazine-1,4-diium bis­(hexa­fluoro­phosphate) dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344619/
https://www.ncbi.nlm.nih.gov/pubmed/22590381
http://dx.doi.org/10.1107/S1600536812017229
work_keys_str_mv AT sunsuwen 14dimethylpiperazine14diiumbishexafluorophosphatedihydrate

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