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(2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate
The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethylformamide solvent molecule is disordered over two orientations...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344624/ https://www.ncbi.nlm.nih.gov/pubmed/22590386 http://dx.doi.org/10.1107/S1600536812017382 |
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author | Annie, C. F. Jacob, Jinsa Mary Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_facet | Annie, C. F. Jacob, Jinsa Mary Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_sort | Annie, C. F. |
collection | PubMed |
description | The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethylformamide solvent molecule is disordered over two orientations with site occupancies of 0.684 (3) and 0.316 (3). The two N atoms of the hydrazinecarboxamide group are involved in intermolecular N—H⋯O hydrogen bonds in which the dimethylformamide O atom acts as acceptor. The structure also features π–π interactions, with a centroid–centroid distance of 3.6561 (13) Å. Classical and non-classical intramolecular O—H⋯N and C—H⋯O hydrogen bonds are also present. |
format | Online Article Text |
id | pubmed-3344624 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33446242012-05-15 (2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate Annie, C. F. Jacob, Jinsa Mary Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethylformamide solvent molecule is disordered over two orientations with site occupancies of 0.684 (3) and 0.316 (3). The two N atoms of the hydrazinecarboxamide group are involved in intermolecular N—H⋯O hydrogen bonds in which the dimethylformamide O atom acts as acceptor. The structure also features π–π interactions, with a centroid–centroid distance of 3.6561 (13) Å. Classical and non-classical intramolecular O—H⋯N and C—H⋯O hydrogen bonds are also present. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344624/ /pubmed/22590386 http://dx.doi.org/10.1107/S1600536812017382 Text en © Annie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Annie, C. F. Jacob, Jinsa Mary Sithambaresan, M. Kurup, M. R. Prathapachandra (2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate |
title | (2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate |
title_full | (2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate |
title_fullStr | (2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate |
title_full_unstemmed | (2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate |
title_short | (2E)-2-[(2-Hydroxy-4-methoxyphenyl)(phenyl)methylidene]-N-phenylhydrazinecarboxamide dimethylformamide monosolvate |
title_sort | (2e)-2-[(2-hydroxy-4-methoxyphenyl)(phenyl)methylidene]-n-phenylhydrazinecarboxamide dimethylformamide monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344624/ https://www.ncbi.nlm.nih.gov/pubmed/22590386 http://dx.doi.org/10.1107/S1600536812017382 |
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