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(2E)-2-[(2-Hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-N-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate

The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethyl­formamide solvent mol­ecule is disordered over two orientations...

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Autores principales: Annie, C. F., Jacob, Jinsa Mary, Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344624/
https://www.ncbi.nlm.nih.gov/pubmed/22590386
http://dx.doi.org/10.1107/S1600536812017382
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author Annie, C. F.
Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Annie, C. F.
Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Annie, C. F.
collection PubMed
description The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethyl­formamide solvent mol­ecule is disordered over two orientations with site occupancies of 0.684 (3) and 0.316 (3). The two N atoms of the hydrazinecarboxamide group are involved in inter­molecular N—H⋯O hydrogen bonds in which the dimethyl­formamide O atom acts as acceptor. The structure also features π–π inter­actions, with a centroid–centroid distance of 3.6561 (13) Å. Classical and non-classical intra­molecular O—H⋯N and C—H⋯O hydrogen bonds are also present.
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spelling pubmed-33446242012-05-15 (2E)-2-[(2-Hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-N-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate Annie, C. F. Jacob, Jinsa Mary Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(21)H(19)N(3)O(3)·C(3)H(7)NO, adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. The dihedral angle between the rings lined to the C=N bond is 88.60 (12)°. The dimethyl­formamide solvent mol­ecule is disordered over two orientations with site occupancies of 0.684 (3) and 0.316 (3). The two N atoms of the hydrazinecarboxamide group are involved in inter­molecular N—H⋯O hydrogen bonds in which the dimethyl­formamide O atom acts as acceptor. The structure also features π–π inter­actions, with a centroid–centroid distance of 3.6561 (13) Å. Classical and non-classical intra­molecular O—H⋯N and C—H⋯O hydrogen bonds are also present. International Union of Crystallography 2012-04-25 /pmc/articles/PMC3344624/ /pubmed/22590386 http://dx.doi.org/10.1107/S1600536812017382 Text en © Annie et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Annie, C. F.
Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
(2E)-2-[(2-Hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-N-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate
title (2E)-2-[(2-Hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-N-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate
title_full (2E)-2-[(2-Hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-N-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate
title_fullStr (2E)-2-[(2-Hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-N-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate
title_full_unstemmed (2E)-2-[(2-Hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-N-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate
title_short (2E)-2-[(2-Hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-N-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate
title_sort (2e)-2-[(2-hy­droxy-4-meth­oxy­phen­yl)(phen­yl)methyl­idene]-n-phenyl­hydrazinecarboxamide dimethyl­formamide monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344624/
https://www.ncbi.nlm.nih.gov/pubmed/22590386
http://dx.doi.org/10.1107/S1600536812017382
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