(E)-3-(2-Chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one

The title compound, C(28)H(19)ClF(2)O(2), is a polysubstituted terphenyl derivative bearing a Michael system in which the C=C double bond has an E conformation. In the crystal, C—H⋯Cl and C—H⋯O contacts connect the mol­ecules into layers lying perpendicular to the a axis. The shortest inter­centroid...

Descripción completa

Detalles Bibliográficos
Autores principales: Samshuddin, S., Narayana, Badiadka, Yathirajan, Hemmige S., Betz, Richard, Gerber, Thomas, Hosten, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344640/
https://www.ncbi.nlm.nih.gov/pubmed/22590402
http://dx.doi.org/10.1107/S1600536812017692
_version_ 1782232037865816064
author Samshuddin, S.
Narayana, Badiadka
Yathirajan, Hemmige S.
Betz, Richard
Gerber, Thomas
Hosten, Eric
author_facet Samshuddin, S.
Narayana, Badiadka
Yathirajan, Hemmige S.
Betz, Richard
Gerber, Thomas
Hosten, Eric
author_sort Samshuddin, S.
collection PubMed
description The title compound, C(28)H(19)ClF(2)O(2), is a polysubstituted terphenyl derivative bearing a Michael system in which the C=C double bond has an E conformation. In the crystal, C—H⋯Cl and C—H⋯O contacts connect the mol­ecules into layers lying perpendicular to the a axis. The shortest inter­centroid distance between symmetry-related 4-fluoro­phenyl groups is 3.7547 (16) Å.
format Online
Article
Text
id pubmed-3344640
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33446402012-05-15 (E)-3-(2-Chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one Samshuddin, S. Narayana, Badiadka Yathirajan, Hemmige S. Betz, Richard Gerber, Thomas Hosten, Eric Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(28)H(19)ClF(2)O(2), is a polysubstituted terphenyl derivative bearing a Michael system in which the C=C double bond has an E conformation. In the crystal, C—H⋯Cl and C—H⋯O contacts connect the mol­ecules into layers lying perpendicular to the a axis. The shortest inter­centroid distance between symmetry-related 4-fluoro­phenyl groups is 3.7547 (16) Å. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344640/ /pubmed/22590402 http://dx.doi.org/10.1107/S1600536812017692 Text en © Samshuddin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Samshuddin, S.
Narayana, Badiadka
Yathirajan, Hemmige S.
Betz, Richard
Gerber, Thomas
Hosten, Eric
(E)-3-(2-Chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one
title (E)-3-(2-Chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one
title_full (E)-3-(2-Chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one
title_fullStr (E)-3-(2-Chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one
title_full_unstemmed (E)-3-(2-Chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one
title_short (E)-3-(2-Chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one
title_sort (e)-3-(2-chloro­phen­yl)-1-(4,4′′-difluoro-5′-meth­oxy-1,1′:3′,1′′-terphenyl-4′-yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344640/
https://www.ncbi.nlm.nih.gov/pubmed/22590402
http://dx.doi.org/10.1107/S1600536812017692
work_keys_str_mv AT samshuddins e32chlorophenyl144difluoro5methoxy1131terphenyl4ylprop2en1one
AT narayanabadiadka e32chlorophenyl144difluoro5methoxy1131terphenyl4ylprop2en1one
AT yathirajanhemmiges e32chlorophenyl144difluoro5methoxy1131terphenyl4ylprop2en1one
AT betzrichard e32chlorophenyl144difluoro5methoxy1131terphenyl4ylprop2en1one
AT gerberthomas e32chlorophenyl144difluoro5methoxy1131terphenyl4ylprop2en1one
AT hosteneric e32chlorophenyl144difluoro5methoxy1131terphenyl4ylprop2en1one

Ejemplares similares