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Butyl 4-(4-methyl­benzene­sulfonamido)­benzoate

In the title compound, C(18)H(21)NO(4)S, the aromatic rings are almost normal to each other, with a dihedral angle of 89.27 (18)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯O inter­action, which generates an S(6) motif. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds lead to...

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Autores principales: Mustafa, Ghulam, Akkurt, Mehmet, Dağdemir, Yılmaz, Khan, Islam Ullah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344642/
https://www.ncbi.nlm.nih.gov/pubmed/22590404
http://dx.doi.org/10.1107/S1600536812015413
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author Mustafa, Ghulam
Akkurt, Mehmet
Dağdemir, Yılmaz
Khan, Islam Ullah
author_facet Mustafa, Ghulam
Akkurt, Mehmet
Dağdemir, Yılmaz
Khan, Islam Ullah
author_sort Mustafa, Ghulam
collection PubMed
description In the title compound, C(18)H(21)NO(4)S, the aromatic rings are almost normal to each other, with a dihedral angle of 89.27 (18)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯O inter­action, which generates an S(6) motif. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds lead to the formation of chains propagating along [010]. Neighbouring chains are linked via a C—H⋯π inter­action. The –CH(2)CH(2)CH(3) atoms of the butyl group are disordered over two sets of sites, with a refined site-occupancy ratio of 0.536 (16):0.464 (16).
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spelling pubmed-33446422012-05-15 Butyl 4-(4-methyl­benzene­sulfonamido)­benzoate Mustafa, Ghulam Akkurt, Mehmet Dağdemir, Yılmaz Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(21)NO(4)S, the aromatic rings are almost normal to each other, with a dihedral angle of 89.27 (18)°. The mol­ecular conformation is stabilized by an intra­molecular C—H⋯O inter­action, which generates an S(6) motif. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds lead to the formation of chains propagating along [010]. Neighbouring chains are linked via a C—H⋯π inter­action. The –CH(2)CH(2)CH(3) atoms of the butyl group are disordered over two sets of sites, with a refined site-occupancy ratio of 0.536 (16):0.464 (16). International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344642/ /pubmed/22590404 http://dx.doi.org/10.1107/S1600536812015413 Text en © Mustafa et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mustafa, Ghulam
Akkurt, Mehmet
Dağdemir, Yılmaz
Khan, Islam Ullah
Butyl 4-(4-methyl­benzene­sulfonamido)­benzoate
title Butyl 4-(4-methyl­benzene­sulfonamido)­benzoate
title_full Butyl 4-(4-methyl­benzene­sulfonamido)­benzoate
title_fullStr Butyl 4-(4-methyl­benzene­sulfonamido)­benzoate
title_full_unstemmed Butyl 4-(4-methyl­benzene­sulfonamido)­benzoate
title_short Butyl 4-(4-methyl­benzene­sulfonamido)­benzoate
title_sort butyl 4-(4-methyl­benzene­sulfonamido)­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344642/
https://www.ncbi.nlm.nih.gov/pubmed/22590404
http://dx.doi.org/10.1107/S1600536812015413
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