Cargando…
Butyl 4-(4-methylbenzenesulfonamido)benzoate
In the title compound, C(18)H(21)NO(4)S, the aromatic rings are almost normal to each other, with a dihedral angle of 89.27 (18)°. The molecular conformation is stabilized by an intramolecular C—H⋯O interaction, which generates an S(6) motif. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds lead to...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344642/ https://www.ncbi.nlm.nih.gov/pubmed/22590404 http://dx.doi.org/10.1107/S1600536812015413 |
_version_ | 1782232038304120832 |
---|---|
author | Mustafa, Ghulam Akkurt, Mehmet Dağdemir, Yılmaz Khan, Islam Ullah |
author_facet | Mustafa, Ghulam Akkurt, Mehmet Dağdemir, Yılmaz Khan, Islam Ullah |
author_sort | Mustafa, Ghulam |
collection | PubMed |
description | In the title compound, C(18)H(21)NO(4)S, the aromatic rings are almost normal to each other, with a dihedral angle of 89.27 (18)°. The molecular conformation is stabilized by an intramolecular C—H⋯O interaction, which generates an S(6) motif. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds lead to the formation of chains propagating along [010]. Neighbouring chains are linked via a C—H⋯π interaction. The –CH(2)CH(2)CH(3) atoms of the butyl group are disordered over two sets of sites, with a refined site-occupancy ratio of 0.536 (16):0.464 (16). |
format | Online Article Text |
id | pubmed-3344642 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33446422012-05-15 Butyl 4-(4-methylbenzenesulfonamido)benzoate Mustafa, Ghulam Akkurt, Mehmet Dağdemir, Yılmaz Khan, Islam Ullah Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(21)NO(4)S, the aromatic rings are almost normal to each other, with a dihedral angle of 89.27 (18)°. The molecular conformation is stabilized by an intramolecular C—H⋯O interaction, which generates an S(6) motif. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds lead to the formation of chains propagating along [010]. Neighbouring chains are linked via a C—H⋯π interaction. The –CH(2)CH(2)CH(3) atoms of the butyl group are disordered over two sets of sites, with a refined site-occupancy ratio of 0.536 (16):0.464 (16). International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344642/ /pubmed/22590404 http://dx.doi.org/10.1107/S1600536812015413 Text en © Mustafa et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mustafa, Ghulam Akkurt, Mehmet Dağdemir, Yılmaz Khan, Islam Ullah Butyl 4-(4-methylbenzenesulfonamido)benzoate |
title | Butyl 4-(4-methylbenzenesulfonamido)benzoate |
title_full | Butyl 4-(4-methylbenzenesulfonamido)benzoate |
title_fullStr | Butyl 4-(4-methylbenzenesulfonamido)benzoate |
title_full_unstemmed | Butyl 4-(4-methylbenzenesulfonamido)benzoate |
title_short | Butyl 4-(4-methylbenzenesulfonamido)benzoate |
title_sort | butyl 4-(4-methylbenzenesulfonamido)benzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344642/ https://www.ncbi.nlm.nih.gov/pubmed/22590404 http://dx.doi.org/10.1107/S1600536812015413 |
work_keys_str_mv | AT mustafaghulam butyl44methylbenzenesulfonamidobenzoate AT akkurtmehmet butyl44methylbenzenesulfonamidobenzoate AT dagdemiryılmaz butyl44methylbenzenesulfonamidobenzoate AT khanislamullah butyl44methylbenzenesulfonamidobenzoate |