(E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide

The title compound, C(14)H(12)ClN(3)O(2), displays an E conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 41.3 (5)°. The mol­ecular structure is stabilized by an intra­molecular O—H⋯N hydrogen bond. In the crystal, N—H⋯O and weak N—H⋯Cl hydrogen bonds...

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Detalles Bibliográficos
Autores principales: Shi, Zhong-Feng, Li, Jia-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344646/
https://www.ncbi.nlm.nih.gov/pubmed/22590408
http://dx.doi.org/10.1107/S160053681201803X
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author Shi, Zhong-Feng
Li, Jia-Ming
author_facet Shi, Zhong-Feng
Li, Jia-Ming
author_sort Shi, Zhong-Feng
collection PubMed
description The title compound, C(14)H(12)ClN(3)O(2), displays an E conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 41.3 (5)°. The mol­ecular structure is stabilized by an intra­molecular O—H⋯N hydrogen bond. In the crystal, N—H⋯O and weak N—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional architecture. In addition, there are weak C—H⋯π stacking inter­actions.
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spelling pubmed-33446462012-05-15 (E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide Shi, Zhong-Feng Li, Jia-Ming Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(12)ClN(3)O(2), displays an E conformation with respect to the C=N double bond. The dihedral angle between the benzene rings is 41.3 (5)°. The mol­ecular structure is stabilized by an intra­molecular O—H⋯N hydrogen bond. In the crystal, N—H⋯O and weak N—H⋯Cl hydrogen bonds link the mol­ecules into a three-dimensional architecture. In addition, there are weak C—H⋯π stacking inter­actions. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344646/ /pubmed/22590408 http://dx.doi.org/10.1107/S160053681201803X Text en © Shi and Li 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shi, Zhong-Feng
Li, Jia-Ming
(E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide
title (E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide
title_full (E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide
title_fullStr (E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide
title_full_unstemmed (E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide
title_short (E)-4-Amino-N′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide
title_sort (e)-4-amino-n′-(5-chloro-2-hy­droxy­benzyl­idene)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344646/
https://www.ncbi.nlm.nih.gov/pubmed/22590408
http://dx.doi.org/10.1107/S160053681201803X
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