Bis(N-methyl-N-phenyl­carbamo­yl)disulfane

The title compound, C(16)H(16)N(2)O(2)S(2), has been synthesized by several different high-yield routes, and has been encountered as a co-product in a number of reaction pathways, ever since it became of inter­est to our research program over 30 years ago. We now confirm the proposed mol­ecular stru...

Descripción completa

Detalles Bibliográficos
Autores principales: Schroll, Alayne L., Pink, Maren, Barany, George
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344649/
https://www.ncbi.nlm.nih.gov/pubmed/22590411
http://dx.doi.org/10.1107/S1600536812016030
_version_ 1782232039893762048
author Schroll, Alayne L.
Pink, Maren
Barany, George
author_facet Schroll, Alayne L.
Pink, Maren
Barany, George
author_sort Schroll, Alayne L.
collection PubMed
description The title compound, C(16)H(16)N(2)O(2)S(2), has been synthesized by several different high-yield routes, and has been encountered as a co-product in a number of reaction pathways, ever since it became of inter­est to our research program over 30 years ago. We now confirm the proposed mol­ecular structure in which the mol­ecule exhibits a twofold axis of symmetry through the mid-point of the S—S bond and the two planes defined by the (carbamo­yl)sulfenyl moieties are essentially perpendicular to each other [dihedral angle = 81.55 (14)°].
format Online
Article
Text
id pubmed-3344649
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33446492012-05-15 Bis(N-methyl-N-phenyl­carbamo­yl)disulfane Schroll, Alayne L. Pink, Maren Barany, George Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(16)N(2)O(2)S(2), has been synthesized by several different high-yield routes, and has been encountered as a co-product in a number of reaction pathways, ever since it became of inter­est to our research program over 30 years ago. We now confirm the proposed mol­ecular structure in which the mol­ecule exhibits a twofold axis of symmetry through the mid-point of the S—S bond and the two planes defined by the (carbamo­yl)sulfenyl moieties are essentially perpendicular to each other [dihedral angle = 81.55 (14)°]. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344649/ /pubmed/22590411 http://dx.doi.org/10.1107/S1600536812016030 Text en © Schroll et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Schroll, Alayne L.
Pink, Maren
Barany, George
Bis(N-methyl-N-phenyl­carbamo­yl)disulfane
title Bis(N-methyl-N-phenyl­carbamo­yl)disulfane
title_full Bis(N-methyl-N-phenyl­carbamo­yl)disulfane
title_fullStr Bis(N-methyl-N-phenyl­carbamo­yl)disulfane
title_full_unstemmed Bis(N-methyl-N-phenyl­carbamo­yl)disulfane
title_short Bis(N-methyl-N-phenyl­carbamo­yl)disulfane
title_sort bis(n-methyl-n-phenyl­carbamo­yl)disulfane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344649/
https://www.ncbi.nlm.nih.gov/pubmed/22590411
http://dx.doi.org/10.1107/S1600536812016030
work_keys_str_mv AT schrollalaynel bisnmethylnphenylcarbamoyldisulfane
AT pinkmaren bisnmethylnphenylcarbamoyldisulfane
AT baranygeorge bisnmethylnphenylcarbamoyldisulfane

Ejemplares similares