Diethyl [(2-bromo­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate

In the title compound, C(26)H(27)BrN(3)O(3)P, the central pyrazole ring forms a dihedral angle of 71.7 (2)° with the bromo­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(10) ring motifs. Four C atoms of the 3-phenyl ring a...

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Autores principales: Suresh, G., Sabari, V., Nandakumar, A., Perumal, P. T., Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344653/
https://www.ncbi.nlm.nih.gov/pubmed/22590415
http://dx.doi.org/10.1107/S1600536812017849
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author Suresh, G.
Sabari, V.
Nandakumar, A.
Perumal, P. T.
Aravindhan, S.
author_facet Suresh, G.
Sabari, V.
Nandakumar, A.
Perumal, P. T.
Aravindhan, S.
author_sort Suresh, G.
collection PubMed
description In the title compound, C(26)H(27)BrN(3)O(3)P, the central pyrazole ring forms a dihedral angle of 71.7 (2)° with the bromo­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(10) ring motifs. Four C atoms of the 3-phenyl ring are disordered over two sets of sites [site occupancies = 0.745 (6) and 0.225 (6)].
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spelling pubmed-33446532012-05-15 Diethyl [(2-bromo­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate Suresh, G. Sabari, V. Nandakumar, A. Perumal, P. T. Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(27)BrN(3)O(3)P, the central pyrazole ring forms a dihedral angle of 71.7 (2)° with the bromo­phenyl ring. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers with R (2) (2)(10) ring motifs. Four C atoms of the 3-phenyl ring are disordered over two sets of sites [site occupancies = 0.745 (6) and 0.225 (6)]. International Union of Crystallography 2012-04-28 /pmc/articles/PMC3344653/ /pubmed/22590415 http://dx.doi.org/10.1107/S1600536812017849 Text en © Suresh et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suresh, G.
Sabari, V.
Nandakumar, A.
Perumal, P. T.
Aravindhan, S.
Diethyl [(2-bromo­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title Diethyl [(2-bromo­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_full Diethyl [(2-bromo­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_fullStr Diethyl [(2-bromo­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_full_unstemmed Diethyl [(2-bromo­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_short Diethyl [(2-bromo­anilino)(1,3-diphenyl-1H-pyrazol-4-yl)meth­yl]phospho­nate
title_sort diethyl [(2-bromo­anilino)(1,3-diphenyl-1h-pyrazol-4-yl)meth­yl]phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344653/
https://www.ncbi.nlm.nih.gov/pubmed/22590415
http://dx.doi.org/10.1107/S1600536812017849
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