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(E)-2-[2-(4-Chlorobenzylidene)hydrazin-1-yl]-4-{[3-(dimethylazaniumyl)propyl]amino}quinazolin-1-ium bis(perchlorate)
In the title compound, C(20)H(25)ClN(6) (2+)·2ClO(4) (−), the organic cation is roughly planar, as shown by the dihedral angle of 3.78 (3)° between the quinazoline and chlorophenyl rings. The quinazoline ring is itself approximately planar, with an average deviation of 0.018 (4) Å. The organic cati...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3344656/ https://www.ncbi.nlm.nih.gov/pubmed/22590418 http://dx.doi.org/10.1107/S1600536812018272 |
Sumario: | In the title compound, C(20)H(25)ClN(6) (2+)·2ClO(4) (−), the organic cation is roughly planar, as shown by the dihedral angle of 3.78 (3)° between the quinazoline and chlorophenyl rings. The quinazoline ring is itself approximately planar, with an average deviation of 0.018 (4) Å. The organic cation adopts an E configuration with respect to the C= N double bond of the hyrazinyl group. The (dimethylazaniumyl)propylamino side chain is disordered over two sets of sites with occupancies of 0.768 (10) and 0.232 (10). In the crystal, two cations and four anions are linked by strong N—H⋯O hydrogen bonds. Weak C—H⋯O hydrogen bonds exist among these aggregates. |
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